skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on K4Ru(NO2)6 by Materials Project

Abstract

Ru(K2(NO2)3)2 crystallizes in the trigonal R-3 space group. The structure is three-dimensional and consists of three rutenio molecules and one K2(NO2)3 framework. In the K2(NO2)3 framework, there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of K–O bond distances ranging from 2.85–3.25 Å. In the second K1+ site, K1+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are three shorter (2.89 Å) and six longer (2.90 Å) K–O bond lengths. N+2.33+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.27 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to three K1+ and one N+2.33+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to three K1+ and one N+2.33+ atom.

Publication Date:
Other Number(s):
mp-557385
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; K4Ru(NO2)6; K-N-O-Ru
OSTI Identifier:
1269815
DOI:
10.17188/1269815

Citation Formats

The Materials Project. Materials Data on K4Ru(NO2)6 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1269815.
The Materials Project. Materials Data on K4Ru(NO2)6 by Materials Project. United States. doi:10.17188/1269815.
The Materials Project. 2020. "Materials Data on K4Ru(NO2)6 by Materials Project". United States. doi:10.17188/1269815. https://www.osti.gov/servlets/purl/1269815. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1269815,
title = {Materials Data on K4Ru(NO2)6 by Materials Project},
author = {The Materials Project},
abstractNote = {Ru(K2(NO2)3)2 crystallizes in the trigonal R-3 space group. The structure is three-dimensional and consists of three rutenio molecules and one K2(NO2)3 framework. In the K2(NO2)3 framework, there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of K–O bond distances ranging from 2.85–3.25 Å. In the second K1+ site, K1+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are three shorter (2.89 Å) and six longer (2.90 Å) K–O bond lengths. N+2.33+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.27 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to three K1+ and one N+2.33+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to three K1+ and one N+2.33+ atom.},
doi = {10.17188/1269815},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

Dataset:

Save / Share: