skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on RbSb2F7 by Materials Project

Abstract

RbSb2F7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to ten F1- atoms. There are a spread of Rb–F bond distances ranging from 2.89–3.39 Å. There are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.99–2.71 Å. In the second Sb3+ site, Sb3+ is bonded to five F1- atoms to form distorted corner-sharing SbF5 square pyramids. There are a spread of Sb–F bond distances ranging from 1.97–2.58 Å. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb3+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Rb1+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to one Rb1+ and two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a 1-coordinate geometry to three equivalent Rb1+ and one Sb3+ atom. In the fifth F1- site, F1- is bonded in a 1-coordinate geometry to threemore » equivalent Rb1+ and one Sb3+ atom. In the sixth F1- site, F1- is bonded in a 2-coordinate geometry to one Rb1+ and two Sb3+ atoms. In the seventh F1- site, F1- is bonded in a distorted single-bond geometry to one Rb1+ and two Sb3+ atoms.« less

Authors:
Contributors:
Researcher:
Publication Date:
Other Number(s):
mp-557260
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbSb2F7; F-Rb-Sb
OSTI Identifier:
1269762
DOI:
10.17188/1269762

Citation Formats

Persson, Kristin, and Project, Materials. Materials Data on RbSb2F7 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1269762.
Persson, Kristin, & Project, Materials. Materials Data on RbSb2F7 by Materials Project. United States. doi:10.17188/1269762.
Persson, Kristin, and Project, Materials. 2020. "Materials Data on RbSb2F7 by Materials Project". United States. doi:10.17188/1269762. https://www.osti.gov/servlets/purl/1269762. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1269762,
title = {Materials Data on RbSb2F7 by Materials Project},
author = {Persson, Kristin and Project, Materials},
abstractNote = {RbSb2F7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to ten F1- atoms. There are a spread of Rb–F bond distances ranging from 2.89–3.39 Å. There are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.99–2.71 Å. In the second Sb3+ site, Sb3+ is bonded to five F1- atoms to form distorted corner-sharing SbF5 square pyramids. There are a spread of Sb–F bond distances ranging from 1.97–2.58 Å. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Sb3+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Rb1+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to one Rb1+ and two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a 1-coordinate geometry to three equivalent Rb1+ and one Sb3+ atom. In the fifth F1- site, F1- is bonded in a 1-coordinate geometry to three equivalent Rb1+ and one Sb3+ atom. In the sixth F1- site, F1- is bonded in a 2-coordinate geometry to one Rb1+ and two Sb3+ atoms. In the seventh F1- site, F1- is bonded in a distorted single-bond geometry to one Rb1+ and two Sb3+ atoms.},
doi = {10.17188/1269762},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}

Dataset:

Save / Share: