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Title: Materials Data on SnCSNF by Materials Project

Abstract

SnCNSF crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two SnCNSF ribbons oriented in the (1, 0, 0) direction. Sn2+ is bonded to one N3- and three equivalent F1- atoms to form a mixture of distorted edge and corner-sharing SnNF3 trigonal pyramids. The Sn–N bond length is 2.22 Å. There are one shorter (2.28 Å) and two longer (2.40 Å) Sn–F bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.19 Å. The C–S bond length is 1.62 Å. N3- is bonded in a distorted linear geometry to one Sn2+ and one C4+ atom. S2- is bonded in a distorted single-bond geometry to one C4+ atom. F1- is bonded in a distorted trigonal planar geometry to three equivalent Sn2+ atoms.

Publication Date:
Other Number(s):
mp-556146
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SnCSNF; C-F-N-S-Sn
OSTI Identifier:
1269195
DOI:
https://doi.org/10.17188/1269195

Citation Formats

The Materials Project. Materials Data on SnCSNF by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1269195.
The Materials Project. Materials Data on SnCSNF by Materials Project. United States. doi:https://doi.org/10.17188/1269195
The Materials Project. 2020. "Materials Data on SnCSNF by Materials Project". United States. doi:https://doi.org/10.17188/1269195. https://www.osti.gov/servlets/purl/1269195. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1269195,
title = {Materials Data on SnCSNF by Materials Project},
author = {The Materials Project},
abstractNote = {SnCNSF crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two SnCNSF ribbons oriented in the (1, 0, 0) direction. Sn2+ is bonded to one N3- and three equivalent F1- atoms to form a mixture of distorted edge and corner-sharing SnNF3 trigonal pyramids. The Sn–N bond length is 2.22 Å. There are one shorter (2.28 Å) and two longer (2.40 Å) Sn–F bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.19 Å. The C–S bond length is 1.62 Å. N3- is bonded in a distorted linear geometry to one Sn2+ and one C4+ atom. S2- is bonded in a distorted single-bond geometry to one C4+ atom. F1- is bonded in a distorted trigonal planar geometry to three equivalent Sn2+ atoms.},
doi = {10.17188/1269195},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}