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Title: Materials Data on Ag5(PbO3)2 by Materials Project

Abstract

Ag5Pb2O6 crystallizes in the trigonal P31m space group. The structure is three-dimensional. there are three inequivalent Ag+1.20+ sites. In the first Ag+1.20+ site, Ag+1.20+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.15 Å. In the second Ag+1.20+ site, Ag+1.20+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.33 Å. In the third Ag+1.20+ site, Ag+1.20+ is bonded in a trigonal non-coplanar geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.36 Å. Pb3+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. All Pb–O bond lengths are 2.28 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two Ag+1.20+ and two equivalent Pb3+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the second O2- site, O2- is bonded to two Ag+1.20+ and two equivalent Pb3+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra.

Authors:
Publication Date:
Other Number(s):
mp-555565
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag5(PbO3)2; Ag-O-Pb
OSTI Identifier:
1268878
DOI:
https://doi.org/10.17188/1268878

Citation Formats

The Materials Project. Materials Data on Ag5(PbO3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1268878.
The Materials Project. Materials Data on Ag5(PbO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1268878
The Materials Project. 2020. "Materials Data on Ag5(PbO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1268878. https://www.osti.gov/servlets/purl/1268878. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1268878,
title = {Materials Data on Ag5(PbO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag5Pb2O6 crystallizes in the trigonal P31m space group. The structure is three-dimensional. there are three inequivalent Ag+1.20+ sites. In the first Ag+1.20+ site, Ag+1.20+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.15 Å. In the second Ag+1.20+ site, Ag+1.20+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.33 Å. In the third Ag+1.20+ site, Ag+1.20+ is bonded in a trigonal non-coplanar geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.36 Å. Pb3+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. All Pb–O bond lengths are 2.28 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two Ag+1.20+ and two equivalent Pb3+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra. In the second O2- site, O2- is bonded to two Ag+1.20+ and two equivalent Pb3+ atoms to form a mixture of corner and edge-sharing OAg2Pb2 tetrahedra.},
doi = {10.17188/1268878},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}