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Title: Materials Data on PH3CS3 by Materials Project

Abstract

CPH3S3 is alpha Niobium phosphide-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CPH3S3 clusters. C2- is bonded in a trigonal non-coplanar geometry to three H1+ and one S2- atom. All C–H bond lengths are 1.10 Å. The C–S bond length is 1.81 Å. P5+ is bonded to four S2- atoms to form edge-sharing PS4 tetrahedra. There are a spread of P–S bond distances ranging from 1.93–2.15 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C2- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C2- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one C2- atom. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a single-bond geometry to one P5+ atom. In the second S2- site, S2- is bonded in a water-like geometry to one C2- and one P5+ atom. In the third S2- site, S2- is bonded in an L-shaped geometry to two equivalent P5+ atoms.

Publication Date:
Other Number(s):
mp-559616
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; PH3CS3; C-H-P-S
OSTI Identifier:
1268569
DOI:
10.17188/1268569

Citation Formats

The Materials Project. Materials Data on PH3CS3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1268569.
The Materials Project. Materials Data on PH3CS3 by Materials Project. United States. doi:10.17188/1268569.
The Materials Project. 2020. "Materials Data on PH3CS3 by Materials Project". United States. doi:10.17188/1268569. https://www.osti.gov/servlets/purl/1268569. Pub date:Wed Jul 22 00:00:00 EDT 2020
@article{osti_1268569,
title = {Materials Data on PH3CS3 by Materials Project},
author = {The Materials Project},
abstractNote = {CPH3S3 is alpha Niobium phosphide-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CPH3S3 clusters. C2- is bonded in a trigonal non-coplanar geometry to three H1+ and one S2- atom. All C–H bond lengths are 1.10 Å. The C–S bond length is 1.81 Å. P5+ is bonded to four S2- atoms to form edge-sharing PS4 tetrahedra. There are a spread of P–S bond distances ranging from 1.93–2.15 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C2- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C2- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one C2- atom. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a single-bond geometry to one P5+ atom. In the second S2- site, S2- is bonded in a water-like geometry to one C2- and one P5+ atom. In the third S2- site, S2- is bonded in an L-shaped geometry to two equivalent P5+ atoms.},
doi = {10.17188/1268569},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

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