U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on VF4 by Materials Project
Abstract
VF4 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one VF4 sheet oriented in the (0, 0, 1) direction. V4+ is bonded to six F1- atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 32°. There is two shorter (1.77 Å) and four longer (1.96 Å) V–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V4+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one V4+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-554799
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; VF4; F-V
- OSTI Identifier:
- 1268105
- DOI:
- https://doi.org/10.17188/1268105
Citation Formats
The Materials Project. Materials Data on VF4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1268105.
The Materials Project. Materials Data on VF4 by Materials Project. United States. doi:https://doi.org/10.17188/1268105
The Materials Project. 2020.
"Materials Data on VF4 by Materials Project". United States. doi:https://doi.org/10.17188/1268105. https://www.osti.gov/servlets/purl/1268105. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1268105,
title = {Materials Data on VF4 by Materials Project},
author = {The Materials Project},
abstractNote = {VF4 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one VF4 sheet oriented in the (0, 0, 1) direction. V4+ is bonded to six F1- atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 32°. There is two shorter (1.77 Å) and four longer (1.96 Å) V–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent V4+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one V4+ atom.},
doi = {10.17188/1268105},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}
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