U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on CsAu2F7 by Materials Project
Abstract
CsAu2F7 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Cs1+ is bonded in a 10-coordinate geometry to ten F1- atoms. There are a spread of Cs–F bond distances ranging from 3.13–3.41 Å. Au3+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There are a spread of Au–F bond distances ranging from 1.94–2.04 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to one Cs1+ and one Au3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Cs1+ and one Au3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Cs1+ and one Au3+ atom. In the fourth F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Au3+ atoms.
- Publication Date:
- Other Number(s):
- mp-554737
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Au-Cs-F; CsAu2F7; crystal structure
- OSTI Identifier:
- 1268071
- DOI:
- https://doi.org/10.17188/1268071
Citation Formats
Materials Data on CsAu2F7 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1268071.
Materials Data on CsAu2F7 by Materials Project. United States. doi:https://doi.org/10.17188/1268071
2020.
"Materials Data on CsAu2F7 by Materials Project". United States. doi:https://doi.org/10.17188/1268071. https://www.osti.gov/servlets/purl/1268071. Pub date:Sat Jul 18 04:00:00 UTC 2020
@article{osti_1268071,
title = {Materials Data on CsAu2F7 by Materials Project},
abstractNote = {CsAu2F7 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Cs1+ is bonded in a 10-coordinate geometry to ten F1- atoms. There are a spread of Cs–F bond distances ranging from 3.13–3.41 Å. Au3+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There are a spread of Au–F bond distances ranging from 1.94–2.04 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to one Cs1+ and one Au3+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Cs1+ and one Au3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to two equivalent Cs1+ and one Au3+ atom. In the fourth F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Au3+ atoms.},
doi = {10.17188/1268071},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}