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Title: Materials Data on Rb2PdN2(ClO2)2 by Materials Project

Abstract

Rb2PdN2(O2Cl)2 crystallizes in the orthorhombic Cmce space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to six equivalent O2- and four equivalent Cl1- atoms. There are a spread of Rb–O bond distances ranging from 3.11–3.37 Å. There are two shorter (3.51 Å) and two longer (3.52 Å) Rb–Cl bond lengths. Pd2+ is bonded in a 6-coordinate geometry to two equivalent N3+ and four equivalent Cl1- atoms. Both Pd–N bond lengths are 2.05 Å. There are two shorter (2.36 Å) and two longer (3.22 Å) Pd–Cl bond lengths. N3+ is bonded in a distorted bent 120 degrees geometry to one Pd2+ and two equivalent O2- atoms. Both N–O bond lengths are 1.25 Å. O2- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one N3+ atom. Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and two equivalent Pd2+ atoms.

Authors:
Contributors:
Researcher:
Publication Date:
Other Number(s):
mp-554602
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rb2PdN2(ClO2)2; Cl-N-O-Pd-Rb
OSTI Identifier:
1267975
DOI:
10.17188/1267975

Citation Formats

Persson, Kristin, and Project, Materials. Materials Data on Rb2PdN2(ClO2)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1267975.
Persson, Kristin, & Project, Materials. Materials Data on Rb2PdN2(ClO2)2 by Materials Project. United States. doi:10.17188/1267975.
Persson, Kristin, and Project, Materials. 2020. "Materials Data on Rb2PdN2(ClO2)2 by Materials Project". United States. doi:10.17188/1267975. https://www.osti.gov/servlets/purl/1267975. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1267975,
title = {Materials Data on Rb2PdN2(ClO2)2 by Materials Project},
author = {Persson, Kristin and Project, Materials},
abstractNote = {Rb2PdN2(O2Cl)2 crystallizes in the orthorhombic Cmce space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to six equivalent O2- and four equivalent Cl1- atoms. There are a spread of Rb–O bond distances ranging from 3.11–3.37 Å. There are two shorter (3.51 Å) and two longer (3.52 Å) Rb–Cl bond lengths. Pd2+ is bonded in a 6-coordinate geometry to two equivalent N3+ and four equivalent Cl1- atoms. Both Pd–N bond lengths are 2.05 Å. There are two shorter (2.36 Å) and two longer (3.22 Å) Pd–Cl bond lengths. N3+ is bonded in a distorted bent 120 degrees geometry to one Pd2+ and two equivalent O2- atoms. Both N–O bond lengths are 1.25 Å. O2- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one N3+ atom. Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and two equivalent Pd2+ atoms.},
doi = {10.17188/1267975},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

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