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Title: Materials Data on CsClO2 by Materials Project

Abstract

CsO2Cl crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Cs is bonded to eight equivalent O atoms to form a mixture of edge, face, and corner-sharing CsO8 hexagonal bipyramids. There are four shorter (3.18 Å) and four longer (3.43 Å) Cs–O bond lengths. O is bonded in a 5-coordinate geometry to four equivalent Cs and one Cl atom. The O–Cl bond length is 1.58 Å. Cl is bonded in a water-like geometry to two equivalent O atoms.

Authors:
Publication Date:
Other Number(s):
mp-552131
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CsClO2; Cl-Cs-O
OSTI Identifier:
1267558
DOI:
https://doi.org/10.17188/1267558

Citation Formats

The Materials Project. Materials Data on CsClO2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1267558.
The Materials Project. Materials Data on CsClO2 by Materials Project. United States. doi:https://doi.org/10.17188/1267558
The Materials Project. 2020. "Materials Data on CsClO2 by Materials Project". United States. doi:https://doi.org/10.17188/1267558. https://www.osti.gov/servlets/purl/1267558. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1267558,
title = {Materials Data on CsClO2 by Materials Project},
author = {The Materials Project},
abstractNote = {CsO2Cl crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Cs is bonded to eight equivalent O atoms to form a mixture of edge, face, and corner-sharing CsO8 hexagonal bipyramids. There are four shorter (3.18 Å) and four longer (3.43 Å) Cs–O bond lengths. O is bonded in a 5-coordinate geometry to four equivalent Cs and one Cl atom. The O–Cl bond length is 1.58 Å. Cl is bonded in a water-like geometry to two equivalent O atoms.},
doi = {10.17188/1267558},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}