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Title: Materials Data on AsS by Materials Project

Abstract

SAs crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four tetraarsenic tetrasulfide molecules. there are two inequivalent As2+ sites. In the first As2+ site, As2+ is bonded in an L-shaped geometry to two S2- atoms. Both As–S bond lengths are 2.26 Å. In the second As2+ site, As2+ is bonded in an L-shaped geometry to two S2- atoms. There are one shorter (2.25 Å) and one longer (2.26 Å) As–S bond lengths. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a water-like geometry to two equivalent As2+ atoms. In the second S2- site, S2- is bonded in a water-like geometry to two equivalent As2+ atoms. In the third S2- site, S2- is bonded in a water-like geometry to two As2+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-542846
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AsS; As-S
OSTI Identifier:
1266759
DOI:
https://doi.org/10.17188/1266759

Citation Formats

The Materials Project. Materials Data on AsS by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1266759.
The Materials Project. Materials Data on AsS by Materials Project. United States. doi:https://doi.org/10.17188/1266759
The Materials Project. 2020. "Materials Data on AsS by Materials Project". United States. doi:https://doi.org/10.17188/1266759. https://www.osti.gov/servlets/purl/1266759. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1266759,
title = {Materials Data on AsS by Materials Project},
author = {The Materials Project},
abstractNote = {SAs crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four tetraarsenic tetrasulfide molecules. there are two inequivalent As2+ sites. In the first As2+ site, As2+ is bonded in an L-shaped geometry to two S2- atoms. Both As–S bond lengths are 2.26 Å. In the second As2+ site, As2+ is bonded in an L-shaped geometry to two S2- atoms. There are one shorter (2.25 Å) and one longer (2.26 Å) As–S bond lengths. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a water-like geometry to two equivalent As2+ atoms. In the second S2- site, S2- is bonded in a water-like geometry to two equivalent As2+ atoms. In the third S2- site, S2- is bonded in a water-like geometry to two As2+ atoms.},
doi = {10.17188/1266759},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}