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Title: Materials Data on Bi9Rh2I3 by Materials Project

Abstract

Rh2Bi9I(I)2 crystallizes in the monoclinic P2_1/m space group. The structure is one-dimensional and consists of four hydriodic acid molecules and one Rh2Bi9I ribbon oriented in the (0, 1, 0) direction. In the Rh2Bi9I ribbon, Rh is bonded in a 8-coordinate geometry to eight Bi atoms. There are a spread of Rh–Bi bond distances ranging from 2.80–2.92 Å. There are six inequivalent Bi sites. In the first Bi site, Bi is bonded in a distorted L-shaped geometry to two equivalent Rh atoms. In the second Bi site, Bi is bonded in an L-shaped geometry to two equivalent Rh and one Bi atom. The Bi–Bi bond length is 3.27 Å. In the third Bi site, Bi is bonded in a 2-coordinate geometry to two equivalent Rh, three Bi, and one I atom. Both Bi–Bi bond lengths are 3.24 Å. The Bi–I bond length is 3.54 Å. In the fourth Bi site, Bi is bonded in a distorted single-bond geometry to one Rh and one Bi atom. In the fifth Bi site, Bi is bonded in a 6-coordinate geometry to two equivalent Rh atoms. In the sixth Bi site, Bi is bonded in a 7-coordinate geometry to two equivalent Rh atoms. I ismore » bonded in a distorted single-bond geometry to one Bi atom.« less

Authors:
Publication Date:
Other Number(s):
mp-541979
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Bi9Rh2I3; Bi-I-Rh
OSTI Identifier:
1266341
DOI:
https://doi.org/10.17188/1266341

Citation Formats

The Materials Project. Materials Data on Bi9Rh2I3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1266341.
The Materials Project. Materials Data on Bi9Rh2I3 by Materials Project. United States. doi:https://doi.org/10.17188/1266341
The Materials Project. 2020. "Materials Data on Bi9Rh2I3 by Materials Project". United States. doi:https://doi.org/10.17188/1266341. https://www.osti.gov/servlets/purl/1266341. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1266341,
title = {Materials Data on Bi9Rh2I3 by Materials Project},
author = {The Materials Project},
abstractNote = {Rh2Bi9I(I)2 crystallizes in the monoclinic P2_1/m space group. The structure is one-dimensional and consists of four hydriodic acid molecules and one Rh2Bi9I ribbon oriented in the (0, 1, 0) direction. In the Rh2Bi9I ribbon, Rh is bonded in a 8-coordinate geometry to eight Bi atoms. There are a spread of Rh–Bi bond distances ranging from 2.80–2.92 Å. There are six inequivalent Bi sites. In the first Bi site, Bi is bonded in a distorted L-shaped geometry to two equivalent Rh atoms. In the second Bi site, Bi is bonded in an L-shaped geometry to two equivalent Rh and one Bi atom. The Bi–Bi bond length is 3.27 Å. In the third Bi site, Bi is bonded in a 2-coordinate geometry to two equivalent Rh, three Bi, and one I atom. Both Bi–Bi bond lengths are 3.24 Å. The Bi–I bond length is 3.54 Å. In the fourth Bi site, Bi is bonded in a distorted single-bond geometry to one Rh and one Bi atom. In the fifth Bi site, Bi is bonded in a 6-coordinate geometry to two equivalent Rh atoms. In the sixth Bi site, Bi is bonded in a 7-coordinate geometry to two equivalent Rh atoms. I is bonded in a distorted single-bond geometry to one Bi atom.},
doi = {10.17188/1266341},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}