Materials Data on Rb2Ge2S5 by Materials Project
Abstract
Rb2Ge2S5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 7-coordinate geometry to seven S2- atoms. There are a spread of Rb–S bond distances ranging from 3.37–3.78 Å. In the second Rb1+ site, Rb1+ is bonded in a 9-coordinate geometry to nine S2- atoms. There are a spread of Rb–S bond distances ranging from 3.39–4.06 Å. There are two inequivalent Ge4+ sites. In the first Ge4+ site, Ge4+ is bonded to four S2- atoms to form corner-sharing GeS4 tetrahedra. There are a spread of Ge–S bond distances ranging from 2.14–2.28 Å. In the second Ge4+ site, Ge4+ is bonded to four S2- atoms to form corner-sharing GeS4 tetrahedra. There are a spread of Ge–S bond distances ranging from 2.14–2.28 Å. There are six inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted water-like geometry to two Rb1+ and two Ge4+ atoms. In the second S2- site, S2- is bonded in a 5-coordinate geometry to three Rb1+ and two Ge4+ atoms. In the third S2- site, S2- is bonded in a 1-coordinate geometry to four Rb1+ and onemore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-541879
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Rb2Ge2S5; Ge-Rb-S
- OSTI Identifier:
- 1266297
- DOI:
- https://doi.org/10.17188/1266297
Citation Formats
The Materials Project. Materials Data on Rb2Ge2S5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1266297.
The Materials Project. Materials Data on Rb2Ge2S5 by Materials Project. United States. doi:https://doi.org/10.17188/1266297
The Materials Project. 2020.
"Materials Data on Rb2Ge2S5 by Materials Project". United States. doi:https://doi.org/10.17188/1266297. https://www.osti.gov/servlets/purl/1266297. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1266297,
title = {Materials Data on Rb2Ge2S5 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb2Ge2S5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 7-coordinate geometry to seven S2- atoms. There are a spread of Rb–S bond distances ranging from 3.37–3.78 Å. In the second Rb1+ site, Rb1+ is bonded in a 9-coordinate geometry to nine S2- atoms. There are a spread of Rb–S bond distances ranging from 3.39–4.06 Å. There are two inequivalent Ge4+ sites. In the first Ge4+ site, Ge4+ is bonded to four S2- atoms to form corner-sharing GeS4 tetrahedra. There are a spread of Ge–S bond distances ranging from 2.14–2.28 Å. In the second Ge4+ site, Ge4+ is bonded to four S2- atoms to form corner-sharing GeS4 tetrahedra. There are a spread of Ge–S bond distances ranging from 2.14–2.28 Å. There are six inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted water-like geometry to two Rb1+ and two Ge4+ atoms. In the second S2- site, S2- is bonded in a 5-coordinate geometry to three Rb1+ and two Ge4+ atoms. In the third S2- site, S2- is bonded in a 1-coordinate geometry to four Rb1+ and one Ge4+ atom. In the fourth S2- site, S2- is bonded in a 1-coordinate geometry to four Rb1+ and one Ge4+ atom. In the fifth S2- site, S2- is bonded in a distorted water-like geometry to four equivalent Rb1+ and two equivalent Ge4+ atoms. In the sixth S2- site, S2- is bonded in a distorted water-like geometry to two equivalent Rb1+ and two equivalent Ge4+ atoms.},
doi = {10.17188/1266297},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}