U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on LiGe2(PO4)3 by Materials Project
Abstract
LiGe2(PO4)3 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Li1+ is bonded in a distorted hexagonal planar geometry to six equivalent O2- atoms. All Li–O bond lengths are 2.23 Å. Ge4+ is bonded to six O2- atoms to form GeO6 octahedra that share corners with six equivalent PO4 tetrahedra. There is three shorter (1.86 Å) and three longer (1.91 Å) Ge–O bond length. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with four equivalent GeO6 octahedra. The corner-sharing octahedra tilt angles range from 26–42°. There is two shorter (1.53 Å) and two longer (1.55 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Ge4+ and one P5+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to one Li1+, one Ge4+, and one P5+ atom.
- Publication Date:
- Other Number(s):
- mp-541272
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ge-Li-O-P; LiGe2(PO4)3; crystal structure
- OSTI Identifier:
- 1265017
- DOI:
- https://doi.org/10.17188/1265017
Citation Formats
Materials Data on LiGe2(PO4)3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1265017.
Materials Data on LiGe2(PO4)3 by Materials Project. United States. doi:https://doi.org/10.17188/1265017
2020.
"Materials Data on LiGe2(PO4)3 by Materials Project". United States. doi:https://doi.org/10.17188/1265017. https://www.osti.gov/servlets/purl/1265017. Pub date:Sun May 03 04:00:00 UTC 2020
@article{osti_1265017,
title = {Materials Data on LiGe2(PO4)3 by Materials Project},
abstractNote = {LiGe2(PO4)3 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Li1+ is bonded in a distorted hexagonal planar geometry to six equivalent O2- atoms. All Li–O bond lengths are 2.23 Å. Ge4+ is bonded to six O2- atoms to form GeO6 octahedra that share corners with six equivalent PO4 tetrahedra. There is three shorter (1.86 Å) and three longer (1.91 Å) Ge–O bond length. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with four equivalent GeO6 octahedra. The corner-sharing octahedra tilt angles range from 26–42°. There is two shorter (1.53 Å) and two longer (1.55 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Ge4+ and one P5+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to one Li1+, one Ge4+, and one P5+ atom.},
doi = {10.17188/1265017},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}