U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on VS4 by Materials Project
Abstract
VS4 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of two VS4 ribbons oriented in the (1, 0, 1) direction. V4+ is bonded to eight S1- atoms to form distorted face-sharing VS8 hexagonal bipyramids. There are a spread of V–S bond distances ranging from 2.39–2.55 Å. There are four inequivalent S1- sites. In the first S1- site, S1- is bonded in a 2-coordinate geometry to two equivalent V4+ and one S1- atom. The S–S bond length is 2.03 Å. In the second S1- site, S1- is bonded in a 2-coordinate geometry to two equivalent V4+ and one S1- atom. In the third S1- site, S1- is bonded in a 3-coordinate geometry to two equivalent V4+ and one S1- atom. The S–S bond length is 2.02 Å. In the fourth S1- site, S1- is bonded in a 3-coordinate geometry to two equivalent V4+ and one S1- atom.
- Publication Date:
- Other Number(s):
- mp-541155
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; S-V; VS4; crystal structure
- OSTI Identifier:
- 1264976
- DOI:
- https://doi.org/10.17188/1264976
Citation Formats
Materials Data on VS4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1264976.
Materials Data on VS4 by Materials Project. United States. doi:https://doi.org/10.17188/1264976
2020.
"Materials Data on VS4 by Materials Project". United States. doi:https://doi.org/10.17188/1264976. https://www.osti.gov/servlets/purl/1264976. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1264976,
title = {Materials Data on VS4 by Materials Project},
abstractNote = {VS4 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of two VS4 ribbons oriented in the (1, 0, 1) direction. V4+ is bonded to eight S1- atoms to form distorted face-sharing VS8 hexagonal bipyramids. There are a spread of V–S bond distances ranging from 2.39–2.55 Å. There are four inequivalent S1- sites. In the first S1- site, S1- is bonded in a 2-coordinate geometry to two equivalent V4+ and one S1- atom. The S–S bond length is 2.03 Å. In the second S1- site, S1- is bonded in a 2-coordinate geometry to two equivalent V4+ and one S1- atom. In the third S1- site, S1- is bonded in a 3-coordinate geometry to two equivalent V4+ and one S1- atom. The S–S bond length is 2.02 Å. In the fourth S1- site, S1- is bonded in a 3-coordinate geometry to two equivalent V4+ and one S1- atom.},
doi = {10.17188/1264976},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}