Materials Data on Ge2C2(SeF2)3 by Materials Project

doi:10.17188/1264969

Title: Materials Data on Ge2C2(SeF2)3 by Materials Project

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Abstract

Ge2C2(SeF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight selenium;trifluoromethylgermanium molecules. Ge4+ is bonded in a trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ge–Se bond lengths are 2.38 Å. C2+ is bonded in a trigonal non-coplanar geometry to three equivalent F1- atoms. All C–F bond lengths are 1.36 Å. Se2- is bonded in a 2-coordinate geometry to two equivalent Ge4+ and two equivalent F1- atoms. Both Se–F bond lengths are 3.28 Å. F1- is bonded in a single-bond geometry to one C2+ and one Se2- atom.

Publication Date:: 2020-05-01

Other Number(s):: mp-541146

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; C-F-Ge-Se; Ge2C2(SeF2)3; crystal structure

OSTI Identifier:: 1264969

DOI:: https://doi.org/10.17188/1264969

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                    Materials Data on Ge2C2(SeF2)3 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1264969.

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                    Materials Data on Ge2C2(SeF2)3 by Materials Project.  United States.  doi:https://doi.org/10.17188/1264969

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                    2020.  
"Materials Data on Ge2C2(SeF2)3 by Materials Project".  United States.  doi:https://doi.org/10.17188/1264969.  https://www.osti.gov/servlets/purl/1264969. Pub date:Fri May 01 00:00:00 EDT 2020

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@article{osti_1264969,

  title        = {Materials Data on Ge2C2(SeF2)3 by Materials Project},

  
  abstractNote = {Ge2C2(SeF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight selenium;trifluoromethylgermanium molecules. Ge4+ is bonded in a trigonal non-coplanar geometry to three equivalent Se2- atoms. All Ge–Se bond lengths are 2.38 Å. C2+ is bonded in a trigonal non-coplanar geometry to three equivalent F1- atoms. All C–F bond lengths are 1.36 Å. Se2- is bonded in a 2-coordinate geometry to two equivalent Ge4+ and two equivalent F1- atoms. Both Se–F bond lengths are 3.28 Å. F1- is bonded in a single-bond geometry to one C2+ and one Se2- atom.},

  doi          = {10.17188/1264969},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1264969

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