U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on CsUN3O11 by Materials Project
Abstract
CsUN3O11 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Cs1+ is bonded in a 8-coordinate geometry to fourteen O2- atoms. There are a spread of Cs–O bond distances ranging from 3.19–3.58 Å. U6+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both U–O bond lengths are 1.80 Å. N5+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.23 Å) and two longer (1.29 Å) N–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to two equivalent Cs1+ and one N5+ atom. In the second O2- site, O2- is bonded in a 1-coordinate geometry to one Cs1+ and one N5+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Cs1+ and one U6+ atom.
- Publication Date:
- Other Number(s):
- mp-541035
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cs-N-O-U; CsUN3O11; crystal structure
- OSTI Identifier:
- 1264922
- DOI:
- https://doi.org/10.17188/1264922
Citation Formats
Materials Data on CsUN3O11 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1264922.
Materials Data on CsUN3O11 by Materials Project. United States. doi:https://doi.org/10.17188/1264922
2020.
"Materials Data on CsUN3O11 by Materials Project". United States. doi:https://doi.org/10.17188/1264922. https://www.osti.gov/servlets/purl/1264922. Pub date:Mon Jul 20 04:00:00 UTC 2020
@article{osti_1264922,
title = {Materials Data on CsUN3O11 by Materials Project},
abstractNote = {CsUN3O11 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Cs1+ is bonded in a 8-coordinate geometry to fourteen O2- atoms. There are a spread of Cs–O bond distances ranging from 3.19–3.58 Å. U6+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both U–O bond lengths are 1.80 Å. N5+ is bonded in a trigonal planar geometry to three O2- atoms. There is one shorter (1.23 Å) and two longer (1.29 Å) N–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to two equivalent Cs1+ and one N5+ atom. In the second O2- site, O2- is bonded in a 1-coordinate geometry to one Cs1+ and one N5+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Cs1+ and one U6+ atom.},
doi = {10.17188/1264922},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jul 20 04:00:00 UTC 2020},
month = {Mon Jul 20 04:00:00 UTC 2020}
}