U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on NaZnSb by Materials Project
Abstract
NaZnSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Na1+ is bonded to five equivalent Sb3- atoms to form distorted NaSb5 trigonal bipyramids that share corners with twelve equivalent ZnSb4 tetrahedra, corners with four equivalent NaSb5 trigonal bipyramids, edges with four equivalent ZnSb4 tetrahedra, and edges with eight equivalent NaSb5 trigonal bipyramids. There are one shorter (3.26 Å) and four longer (3.29 Å) Na–Sb bond lengths. Zn2+ is bonded to four equivalent Sb3- atoms to form ZnSb4 tetrahedra that share corners with four equivalent ZnSb4 tetrahedra, corners with twelve equivalent NaSb5 trigonal bipyramids, edges with four equivalent ZnSb4 tetrahedra, and edges with four equivalent NaSb5 trigonal bipyramids. All Zn–Sb bond lengths are 2.80 Å. Sb3- is bonded in a 9-coordinate geometry to five equivalent Na1+ and four equivalent Zn2+ atoms.
- Publication Date:
- Other Number(s):
- mp-4247
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Na-Sb-Zn; NaZnSb; crystal structure
- OSTI Identifier:
- 1207997
- DOI:
- https://doi.org/10.17188/1207997
Citation Formats
Materials Data on NaZnSb by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1207997.
Materials Data on NaZnSb by Materials Project. United States. doi:https://doi.org/10.17188/1207997
2020.
"Materials Data on NaZnSb by Materials Project". United States. doi:https://doi.org/10.17188/1207997. https://www.osti.gov/servlets/purl/1207997. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1207997,
title = {Materials Data on NaZnSb by Materials Project},
abstractNote = {NaZnSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Na1+ is bonded to five equivalent Sb3- atoms to form distorted NaSb5 trigonal bipyramids that share corners with twelve equivalent ZnSb4 tetrahedra, corners with four equivalent NaSb5 trigonal bipyramids, edges with four equivalent ZnSb4 tetrahedra, and edges with eight equivalent NaSb5 trigonal bipyramids. There are one shorter (3.26 Å) and four longer (3.29 Å) Na–Sb bond lengths. Zn2+ is bonded to four equivalent Sb3- atoms to form ZnSb4 tetrahedra that share corners with four equivalent ZnSb4 tetrahedra, corners with twelve equivalent NaSb5 trigonal bipyramids, edges with four equivalent ZnSb4 tetrahedra, and edges with four equivalent NaSb5 trigonal bipyramids. All Zn–Sb bond lengths are 2.80 Å. Sb3- is bonded in a 9-coordinate geometry to five equivalent Na1+ and four equivalent Zn2+ atoms.},
doi = {10.17188/1207997},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}