Materials Data on RbFe2S3 by Materials Project
Abstract
RbFe2S3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to ten S2- atoms. There are a spread of Rb–S bond distances ranging from 3.44–3.86 Å. Fe+2.50+ is bonded to four S2- atoms to form a mixture of corner and edge-sharing FeS4 tetrahedra. There are two shorter (2.12 Å) and two longer (2.18 Å) Fe–S bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a 6-coordinate geometry to two equivalent Rb1+ and four equivalent Fe+2.50+ atoms. In the second S2- site, S2- is bonded in a 2-coordinate geometry to four equivalent Rb1+ and two equivalent Fe+2.50+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-3787
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; RbFe2S3; Fe-Rb-S
- OSTI Identifier:
- 1207427
- DOI:
- https://doi.org/10.17188/1207427
Citation Formats
The Materials Project. Materials Data on RbFe2S3 by Materials Project. United States: N. p., 2017.
Web. doi:10.17188/1207427.
The Materials Project. Materials Data on RbFe2S3 by Materials Project. United States. doi:https://doi.org/10.17188/1207427
The Materials Project. 2017.
"Materials Data on RbFe2S3 by Materials Project". United States. doi:https://doi.org/10.17188/1207427. https://www.osti.gov/servlets/purl/1207427. Pub date:Thu May 11 00:00:00 EDT 2017
@article{osti_1207427,
title = {Materials Data on RbFe2S3 by Materials Project},
author = {The Materials Project},
abstractNote = {RbFe2S3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to ten S2- atoms. There are a spread of Rb–S bond distances ranging from 3.44–3.86 Å. Fe+2.50+ is bonded to four S2- atoms to form a mixture of corner and edge-sharing FeS4 tetrahedra. There are two shorter (2.12 Å) and two longer (2.18 Å) Fe–S bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a 6-coordinate geometry to two equivalent Rb1+ and four equivalent Fe+2.50+ atoms. In the second S2- site, S2- is bonded in a 2-coordinate geometry to four equivalent Rb1+ and two equivalent Fe+2.50+ atoms.},
doi = {10.17188/1207427},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2017},
month = {5}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.