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Title: Materials Data on P2S2O3 by Materials Project

Abstract

P2S2O3 is alpha Po structured and crystallizes in the tetragonal I-4c2 space group. The structure is zero-dimensional and consists of four P2S2O3 clusters. P5+ is bonded to one S2- and three O2- atoms to form distorted corner-sharing PSO3 tetrahedra. The P–S bond length is 1.87 Å. All P–O bond lengths are 1.64 Å. S2- is bonded in a single-bond geometry to one P5+ atom. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to two equivalent P5+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to two equivalent P5+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-3667
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; P2S2O3; O-P-S
OSTI Identifier:
1207211
DOI:
https://doi.org/10.17188/1207211

Citation Formats

The Materials Project. Materials Data on P2S2O3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1207211.
The Materials Project. Materials Data on P2S2O3 by Materials Project. United States. doi:https://doi.org/10.17188/1207211
The Materials Project. 2020. "Materials Data on P2S2O3 by Materials Project". United States. doi:https://doi.org/10.17188/1207211. https://www.osti.gov/servlets/purl/1207211. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1207211,
title = {Materials Data on P2S2O3 by Materials Project},
author = {The Materials Project},
abstractNote = {P2S2O3 is alpha Po structured and crystallizes in the tetragonal I-4c2 space group. The structure is zero-dimensional and consists of four P2S2O3 clusters. P5+ is bonded to one S2- and three O2- atoms to form distorted corner-sharing PSO3 tetrahedra. The P–S bond length is 1.87 Å. All P–O bond lengths are 1.64 Å. S2- is bonded in a single-bond geometry to one P5+ atom. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to two equivalent P5+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to two equivalent P5+ atoms.},
doi = {10.17188/1207211},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}