Materials Data on U(SbO3)2 by Materials Project

doi:10.17188/1205539

Title: Materials Data on U(SbO3)2 by Materials Project

Dataset
Other Related Research

Abstract

U(SbO3)2 crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one U(SbO3)2 sheet oriented in the (0, 0, 1) direction. U6+ is bonded in a 2-coordinate geometry to six O2- atoms. There are two shorter (1.84 Å) and four longer (2.37 Å) U–O bond lengths. Sb3+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 1.99–2.17 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one U6+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sb3+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two equivalent U6+ and one Sb3+ atom.

Publication Date:: 2017-05-10

Other Number(s):: mp-31256

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; O-Sb-U; U(SbO3)2; crystal structure

OSTI Identifier:: 1205539

DOI:: https://doi.org/10.17188/1205539

Citation Formats


                    Materials Data on U(SbO3)2 by Materials Project.  United States: N. p., 2017. 
        Web.  doi:10.17188/1205539.

Copy to clipboard


                    Materials Data on U(SbO3)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1205539

Copy to clipboard


                    2017.  
"Materials Data on U(SbO3)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1205539.  https://www.osti.gov/servlets/purl/1205539. Pub date:Wed May 10 00:00:00 EDT 2017

Copy to clipboard


                    
@article{osti_1205539,

  title        = {Materials Data on U(SbO3)2 by Materials Project},

  
  abstractNote = {U(SbO3)2 crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one U(SbO3)2 sheet oriented in the (0, 0, 1) direction. U6+ is bonded in a 2-coordinate geometry to six O2- atoms. There are two shorter (1.84 Å) and four longer (2.37 Å) U–O bond lengths. Sb3+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 1.99–2.17 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one U6+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sb3+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two equivalent U6+ and one Sb3+ atom.},

  doi          = {10.17188/1205539},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {5}

}

Copy to clipboard

Dataset:

View Dataset

DOI: https://doi.org/10.17188/1205539

Save / Share:

Export Metadata

Save to My Library

Similar records in DOE Data Explorer and OSTI.GOV collections:

Materials Data on Mn(SbO3)2 by Materials Project

Dataset

MnSb2O6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is three-dimensional. Mn2+ is bonded to six O2- atoms to form MnO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 52–53°. There are a spread of Mn–O bond distances ranging from 2.13–2.16 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with four equivalent MnO6 octahedra, corners with four equivalent SbO6 octahedra, an edgeedge with one MnO6 octahedra, and an edgeedge with one SbO6 octahedra.more »« less
Materials Data on Hg(SbO3)2 by Materials Project

Dataset

Hg(SbO3)2 is zeta iron carbide-derived structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Hg2+ is bonded to six O2- atoms to form HgO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 54–57°. There are two shorter (2.27 Å) and four longer (2.35 Å) Hg–O bond lengths. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with four equivalent HgO6 octahedra, corners with four equivalent SbO6 octahedra, an edgeedge with one HgO6 octahedra, and an edgeedgemore »« less
Materials Data on Ni(SbO3)2 by Materials Project

Dataset

NiSb2O6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Ni2+ is bonded to six O2- atoms to form NiO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 51°. All Ni–O bond lengths are 2.07 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with four equivalent NiO6 octahedra, corners with four equivalent SbO6 octahedra, an edgeedge with one NiO6 octahedra, and an edgeedge with one SbO6 octahedra. The corner-sharing octahedra tilt angles rangemore »« less
Materials Data on Hg(SbO3)2 by Materials Project

Dataset

Hg(SbO3)2 is zeta iron carbide-derived structured and crystallizes in the trigonal P-31m space group. The structure is three-dimensional. Hg2+ is bonded to six equivalent O2- atoms to form HgO6 octahedra that share corners with twelve equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Hg–O bond lengths are 2.44 Å. Sb5+ is bonded to six equivalent O2- atoms to form SbO6 octahedra that share corners with six equivalent HgO6 octahedra and edges with three equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Sb–O bond lengths are 2.02 Å. O2- is bonded in a distorted trigonalmore »« less
Materials Data on Zn(SbO3)2 by Materials Project

Dataset

ZnSb2O6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Zn2+ is bonded to six O2- atoms to form ZnO6 octahedra that share corners with eight equivalent SbO6 octahedra and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 51–52°. There are two shorter (2.09 Å) and four longer (2.11 Å) Zn–O bond lengths. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with four equivalent ZnO6 octahedra, corners with four equivalent SbO6 octahedra, an edgeedge with one ZnO6 octahedra, and an edgeedge with onemore »« less

Similar Records