Materials Data on Sn(NO3)4 by Materials Project
Abstract
Sn(NO3)4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trinitrooxystannyl nitrate molecules. Sn4+ is bonded in a distorted hexagonal bipyramidal geometry to eight O2- atoms. There are a spread of Sn–O bond distances ranging from 2.18–2.24 Å. There are four inequivalent N5+ sites. In the first N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.21–1.33 Å. In the second N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.21–1.33 Å. In the third N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.21–1.33 Å. In the fourth N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.20–1.33 Å. There are twelve inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the second O2- site, O2- is bonded in an L-shaped geometrymore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-30989
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sn(NO3)4; N-O-Sn
- OSTI Identifier:
- 1205324
- DOI:
- https://doi.org/10.17188/1205324
Citation Formats
The Materials Project. Materials Data on Sn(NO3)4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1205324.
The Materials Project. Materials Data on Sn(NO3)4 by Materials Project. United States. doi:https://doi.org/10.17188/1205324
The Materials Project. 2020.
"Materials Data on Sn(NO3)4 by Materials Project". United States. doi:https://doi.org/10.17188/1205324. https://www.osti.gov/servlets/purl/1205324. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1205324,
title = {Materials Data on Sn(NO3)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Sn(NO3)4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trinitrooxystannyl nitrate molecules. Sn4+ is bonded in a distorted hexagonal bipyramidal geometry to eight O2- atoms. There are a spread of Sn–O bond distances ranging from 2.18–2.24 Å. There are four inequivalent N5+ sites. In the first N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.21–1.33 Å. In the second N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.21–1.33 Å. In the third N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.21–1.33 Å. In the fourth N5+ site, N5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of N–O bond distances ranging from 1.20–1.33 Å. There are twelve inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the second O2- site, O2- is bonded in an L-shaped geometry to one Sn4+ and one N5+ atom. In the third O2- site, O2- is bonded in a distorted L-shaped geometry to one Sn4+ and one N5+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the fifth O2- site, O2- is bonded in an L-shaped geometry to one Sn4+ and one N5+ atom. In the sixth O2- site, O2- is bonded in an L-shaped geometry to one Sn4+ and one N5+ atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the eighth O2- site, O2- is bonded in a distorted L-shaped geometry to one Sn4+ and one N5+ atom. In the ninth O2- site, O2- is bonded in a distorted L-shaped geometry to one Sn4+ and one N5+ atom. In the tenth O2- site, O2- is bonded in a distorted L-shaped geometry to one Sn4+ and one N5+ atom. In the eleventh O2- site, O2- is bonded in a single-bond geometry to one N5+ atom. In the twelfth O2- site, O2- is bonded in an L-shaped geometry to one Sn4+ and one N5+ atom.},
doi = {10.17188/1205324},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}