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Title: Materials Data on Ag2SO3 by Materials Project

Abstract

Ag2SO3 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a distorted see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.32–2.57 Å. In the second Ag1+ site, Ag1+ is bonded in a 5-coordinate geometry to one S4+ and four O2- atoms. The Ag–S bond length is 2.51 Å. There are a spread of Ag–O bond distances ranging from 2.45–2.88 Å. S4+ is bonded in a trigonal non-coplanar geometry to one Ag1+ and three O2- atoms. There are a spread of S–O bond distances ranging from 1.52–1.54 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one S4+ atom. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to two Ag1+ and one S4+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to three Ag1+ and one S4+ atom.

Authors:
Publication Date:
Other Number(s):
mp-30982
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag2SO3; Ag-O-S
OSTI Identifier:
1205318
DOI:
https://doi.org/10.17188/1205318

Citation Formats

The Materials Project. Materials Data on Ag2SO3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1205318.
The Materials Project. Materials Data on Ag2SO3 by Materials Project. United States. doi:https://doi.org/10.17188/1205318
The Materials Project. 2020. "Materials Data on Ag2SO3 by Materials Project". United States. doi:https://doi.org/10.17188/1205318. https://www.osti.gov/servlets/purl/1205318. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1205318,
title = {Materials Data on Ag2SO3 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag2SO3 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a distorted see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.32–2.57 Å. In the second Ag1+ site, Ag1+ is bonded in a 5-coordinate geometry to one S4+ and four O2- atoms. The Ag–S bond length is 2.51 Å. There are a spread of Ag–O bond distances ranging from 2.45–2.88 Å. S4+ is bonded in a trigonal non-coplanar geometry to one Ag1+ and three O2- atoms. There are a spread of S–O bond distances ranging from 1.52–1.54 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one S4+ atom. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to two Ag1+ and one S4+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to three Ag1+ and one S4+ atom.},
doi = {10.17188/1205318},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}