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Title: Materials Data on IO2F by Materials Project

Abstract

O2IF crystallizes in the orthorhombic P2_12_12_1 space group. The structure is one-dimensional and consists of two O2IF ribbons oriented in the (0, 1, 0) direction. there are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent I5+ atoms. There are one shorter (1.84 Å) and one longer (2.23 Å) O–I bond lengths. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one I5+ atom. The O–I bond length is 1.79 Å. I5+ is bonded in a 4-coordinate geometry to three O2- and one F1- atom. The I–F bond length is 1.95 Å. F1- is bonded in a single-bond geometry to one I5+ atom.

Authors:
Publication Date:
Other Number(s):
mp-29946
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; IO2F; F-I-O
OSTI Identifier:
1204380
DOI:
https://doi.org/10.17188/1204380

Citation Formats

The Materials Project. Materials Data on IO2F by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1204380.
The Materials Project. Materials Data on IO2F by Materials Project. United States. doi:https://doi.org/10.17188/1204380
The Materials Project. 2020. "Materials Data on IO2F by Materials Project". United States. doi:https://doi.org/10.17188/1204380. https://www.osti.gov/servlets/purl/1204380. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1204380,
title = {Materials Data on IO2F by Materials Project},
author = {The Materials Project},
abstractNote = {O2IF crystallizes in the orthorhombic P2_12_12_1 space group. The structure is one-dimensional and consists of two O2IF ribbons oriented in the (0, 1, 0) direction. there are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent I5+ atoms. There are one shorter (1.84 Å) and one longer (2.23 Å) O–I bond lengths. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one I5+ atom. The O–I bond length is 1.79 Å. I5+ is bonded in a 4-coordinate geometry to three O2- and one F1- atom. The I–F bond length is 1.95 Å. F1- is bonded in a single-bond geometry to one I5+ atom.},
doi = {10.17188/1204380},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}