Materials Data on Tl(ZnSb)2 by Materials Project

doi:10.17188/1204208

Title: Materials Data on Tl(ZnSb)2 by Materials Project

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Abstract

Tl(ZnSb)2 crystallizes in the tetragonal I4cm space group. The structure is three-dimensional and consists of two Tl ribbons oriented in the (0, 0, 1) direction and one ZnSb framework. In each Tl ribbon, Tl1+ is bonded in a 2-coordinate geometry to two equivalent Tl1+ atoms. Both Tl–Tl bond lengths are 3.74 Å. In the ZnSb framework, Zn2+ is bonded to four equivalent Sb+2.50- atoms to form a mixture of corner and edge-sharing ZnSb4 tetrahedra. There are a spread of Zn–Sb bond distances ranging from 2.67–2.74 Å. Sb+2.50- is bonded to four equivalent Zn2+ atoms to form a mixture of corner and edge-sharing SbZn4 tetrahedra.

Authors:: The Materials Project

Publication Date:: 2020-05-03

Other Number(s):: mp-29740

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Tl(ZnSb)2; Sb-Tl-Zn

OSTI Identifier:: 1204208

DOI:: https://doi.org/10.17188/1204208

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                    The Materials Project. Materials Data on Tl(ZnSb)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1204208.

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                    The Materials Project. Materials Data on Tl(ZnSb)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1204208

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                    The Materials Project. 2020.  
"Materials Data on Tl(ZnSb)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1204208.  https://www.osti.gov/servlets/purl/1204208. Pub date:Sun May 03 00:00:00 EDT 2020

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@article{osti_1204208,

  title        = {Materials Data on Tl(ZnSb)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Tl(ZnSb)2 crystallizes in the tetragonal I4cm space group. The structure is three-dimensional and consists of two Tl ribbons oriented in the (0, 0, 1) direction and one ZnSb framework. In each Tl ribbon, Tl1+ is bonded in a 2-coordinate geometry to two equivalent Tl1+ atoms. Both Tl–Tl bond lengths are 3.74 Å. In the ZnSb framework, Zn2+ is bonded to four equivalent Sb+2.50- atoms to form a mixture of corner and edge-sharing ZnSb4 tetrahedra. There are a spread of Zn–Sb bond distances ranging from 2.67–2.74 Å. Sb+2.50- is bonded to four equivalent Zn2+ atoms to form a mixture of corner and edge-sharing SbZn4 tetrahedra.},

  doi          = {10.17188/1204208},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1204208

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