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Title: Materials Data on AgC4N3 by Materials Project

Abstract

Ag(CN)3C crystallizes in the orthorhombic Ima2 space group. The structure is zero-dimensional and consists of four methane molecules and four Ag(CN)3 clusters. In each Ag(CN)3 cluster, Ag1+ is bonded in a trigonal planar geometry to three N3- atoms. There are one shorter (2.14 Å) and two longer (2.24 Å) Ag–N bond lengths. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a bent 150 degrees geometry to one Ag1+ and one C2+ atom. In the second N3- site, N3- is bonded in a linear geometry to one Ag1+ and one C2+ atom.

Authors:
Publication Date:
Other Number(s):
mp-29672
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AgC4N3; Ag-C-N
OSTI Identifier:
1204153
DOI:
https://doi.org/10.17188/1204153

Citation Formats

The Materials Project. Materials Data on AgC4N3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1204153.
The Materials Project. Materials Data on AgC4N3 by Materials Project. United States. doi:https://doi.org/10.17188/1204153
The Materials Project. 2020. "Materials Data on AgC4N3 by Materials Project". United States. doi:https://doi.org/10.17188/1204153. https://www.osti.gov/servlets/purl/1204153. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1204153,
title = {Materials Data on AgC4N3 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag(CN)3C crystallizes in the orthorhombic Ima2 space group. The structure is zero-dimensional and consists of four methane molecules and four Ag(CN)3 clusters. In each Ag(CN)3 cluster, Ag1+ is bonded in a trigonal planar geometry to three N3- atoms. There are one shorter (2.14 Å) and two longer (2.24 Å) Ag–N bond lengths. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a bent 150 degrees geometry to one Ag1+ and one C2+ atom. In the second N3- site, N3- is bonded in a linear geometry to one Ag1+ and one C2+ atom.},
doi = {10.17188/1204153},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}