U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Rb6Cl4O by Materials Project
Abstract
Rb6OCl4 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Rb1+ is bonded to one O2- and five Cl1- atoms to form a mixture of distorted edge, face, and corner-sharing RbCl5O octahedra. The corner-sharing octahedra tilt angles range from 0–63°. The Rb–O bond length is 2.72 Å. There are a spread of Rb–Cl bond distances ranging from 3.29–3.61 Å. O2- is bonded in an octahedral geometry to six equivalent Rb1+ atoms. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 6-coordinate geometry to six equivalent Rb1+ atoms. In the second Cl1- site, Cl1- is bonded in a 8-coordinate geometry to eight equivalent Rb1+ atoms.
- Publication Date:
- Other Number(s):
- mp-29468
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cl-O-Rb; Rb6Cl4O; crystal structure
- OSTI Identifier:
- 1203950
- DOI:
- https://doi.org/10.17188/1203950
Citation Formats
Materials Data on Rb6Cl4O by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1203950.
Materials Data on Rb6Cl4O by Materials Project. United States. doi:https://doi.org/10.17188/1203950
2020.
"Materials Data on Rb6Cl4O by Materials Project". United States. doi:https://doi.org/10.17188/1203950. https://www.osti.gov/servlets/purl/1203950. Pub date:Mon Jul 20 00:00:00 EDT 2020
@article{osti_1203950,
title = {Materials Data on Rb6Cl4O by Materials Project},
abstractNote = {Rb6OCl4 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Rb1+ is bonded to one O2- and five Cl1- atoms to form a mixture of distorted edge, face, and corner-sharing RbCl5O octahedra. The corner-sharing octahedra tilt angles range from 0–63°. The Rb–O bond length is 2.72 Å. There are a spread of Rb–Cl bond distances ranging from 3.29–3.61 Å. O2- is bonded in an octahedral geometry to six equivalent Rb1+ atoms. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 6-coordinate geometry to six equivalent Rb1+ atoms. In the second Cl1- site, Cl1- is bonded in a 8-coordinate geometry to eight equivalent Rb1+ atoms.},
doi = {10.17188/1203950},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.