Search Navigation Menu
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scientific Data

Title: Materials Data on Sb7F29 by Materials Project

Abstract

Sb7F29 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two Sb7F29 ribbons oriented in the (1, 0, 0) direction. there are seven inequivalent Sb+4.14+ sites. In the first Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form distorted corner-sharing SbF6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 23–52°. There are a spread of Sb–F bond distances ranging from 1.89–2.34 Å. In the second Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. There are a spread of Sb–F bond distances ranging from 1.89–2.02 Å. In the third Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. There are a spread of Sb–F bond distances ranging from 1.88–2.04 Å. In the fourth Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. There are a spread of Sb–F bond distances ranging from 1.88–2.03 Å. In the fifth Sb+4.14+ site, Sb+4.14+ is bonded in a 4-coordinate geometry to four F1- atoms. There are a spread of Sb–F bond distances ranging from 1.91–2.34 Å. In the sixth Sb+4.14+ site, Sb+4.14+ is bonded in a 4-coordinate geometry to six F1-more » atoms. There are a spread of Sb–F bond distances ranging from 1.91–2.72 Å. In the seventh Sb+4.14+ site, Sb+4.14+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.89–1.98 Å. There are twenty-nine inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to two Sb+4.14+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the sixth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the seventh F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the eighth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Sb+4.14+ atoms. In the ninth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the tenth F1- site, F1- is bonded in a distorted linear geometry to two Sb+4.14+ atoms. In the eleventh F1- site, F1- is bonded in a bent 150 degrees geometry to two Sb+4.14+ atoms. In the twelfth F1- site, F1- is bonded in a bent 150 degrees geometry to two Sb+4.14+ atoms. In the thirteenth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the fourteenth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the fifteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the sixteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the seventeenth F1- site, F1- is bonded in a single-bond geometry to two Sb+4.14+ atoms. In the eighteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the nineteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twentieth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-first F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-second F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-third F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-fourth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-fifth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-sixth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-seventh F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-eighth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-ninth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom.« less

Authors:
Publication Date:
Other Number(s):
mp-29369
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sb7F29; F-Sb
OSTI Identifier:
1203716
DOI:
https://doi.org/10.17188/1203716

Citation Formats

The Materials Project. Materials Data on Sb7F29 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1203716.
Copy to clipboard
The Materials Project. Materials Data on Sb7F29 by Materials Project. United States. doi:https://doi.org/10.17188/1203716
Copy to clipboard
The Materials Project. 2020. "Materials Data on Sb7F29 by Materials Project". United States. doi:https://doi.org/10.17188/1203716. https://www.osti.gov/servlets/purl/1203716. Pub date:Sat May 02 00:00:00 EDT 2020
Copy to clipboard
@article{osti_1203716,
title = {Materials Data on Sb7F29 by Materials Project},
author = {The Materials Project},
abstractNote = {Sb7F29 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of two Sb7F29 ribbons oriented in the (1, 0, 0) direction. there are seven inequivalent Sb+4.14+ sites. In the first Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form distorted corner-sharing SbF6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 23–52°. There are a spread of Sb–F bond distances ranging from 1.89–2.34 Å. In the second Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. There are a spread of Sb–F bond distances ranging from 1.89–2.02 Å. In the third Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. There are a spread of Sb–F bond distances ranging from 1.88–2.04 Å. In the fourth Sb+4.14+ site, Sb+4.14+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. There are a spread of Sb–F bond distances ranging from 1.88–2.03 Å. In the fifth Sb+4.14+ site, Sb+4.14+ is bonded in a 4-coordinate geometry to four F1- atoms. There are a spread of Sb–F bond distances ranging from 1.91–2.34 Å. In the sixth Sb+4.14+ site, Sb+4.14+ is bonded in a 4-coordinate geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.91–2.72 Å. In the seventh Sb+4.14+ site, Sb+4.14+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.89–1.98 Å. There are twenty-nine inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted single-bond geometry to two Sb+4.14+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the sixth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the seventh F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the eighth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Sb+4.14+ atoms. In the ninth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the tenth F1- site, F1- is bonded in a distorted linear geometry to two Sb+4.14+ atoms. In the eleventh F1- site, F1- is bonded in a bent 150 degrees geometry to two Sb+4.14+ atoms. In the twelfth F1- site, F1- is bonded in a bent 150 degrees geometry to two Sb+4.14+ atoms. In the thirteenth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the fourteenth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Sb+4.14+ atoms. In the fifteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the sixteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the seventeenth F1- site, F1- is bonded in a single-bond geometry to two Sb+4.14+ atoms. In the eighteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the nineteenth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twentieth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-first F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-second F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-third F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-fourth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-fifth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-sixth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-seventh F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-eighth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom. In the twenty-ninth F1- site, F1- is bonded in a single-bond geometry to one Sb+4.14+ atom.},
doi = {10.17188/1203716},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}
Copy to clipboard
Dataset:
View Dataset
DOI: https://doi.org/10.17188/1203716
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Similar records in DOE Data Explorer and OSTI.GOV collections: