U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Rb2PuCl5 by Materials Project
Abstract
Rb2PuCl5 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.31–3.55 Å. Pu3+ is bonded to seven Cl1- atoms to form distorted edge-sharing PuCl7 pentagonal bipyramids. There are a spread of Pu–Cl bond distances ranging from 2.75–2.88 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Pu3+ atoms. In the second Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Pu3+ atom. In the third Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Pu3+ atom. In the fourth Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Pu3+ atom.
- Publication Date:
- Other Number(s):
- mp-29333
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cl-Pu-Rb; Rb2PuCl5; crystal structure
- OSTI Identifier:
- 1203691
- DOI:
- https://doi.org/10.17188/1203691
Citation Formats
Materials Data on Rb2PuCl5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1203691.
Materials Data on Rb2PuCl5 by Materials Project. United States. doi:https://doi.org/10.17188/1203691
2020.
"Materials Data on Rb2PuCl5 by Materials Project". United States. doi:https://doi.org/10.17188/1203691. https://www.osti.gov/servlets/purl/1203691. Pub date:Sat May 02 04:00:00 UTC 2020
@article{osti_1203691,
title = {Materials Data on Rb2PuCl5 by Materials Project},
abstractNote = {Rb2PuCl5 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.31–3.55 Å. Pu3+ is bonded to seven Cl1- atoms to form distorted edge-sharing PuCl7 pentagonal bipyramids. There are a spread of Pu–Cl bond distances ranging from 2.75–2.88 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Pu3+ atoms. In the second Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Pu3+ atom. In the third Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Pu3+ atom. In the fourth Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Pu3+ atom.},
doi = {10.17188/1203691},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}