U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on NaSbF4 by Materials Project
Abstract
NaSbF4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Na1+ is bonded to six F1- atoms to form distorted corner-sharing NaF6 octahedra. The corner-sharing octahedra tilt angles range from 52–64°. There are a spread of Na–F bond distances ranging from 2.30–2.49 Å. Sb3+ is bonded in a 5-coordinate geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 2.00–2.53 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted trigonal planar geometry to two equivalent Na1+ and one Sb3+ atom. In the second F1- site, F1- is bonded in a trigonal planar geometry to two equivalent Na1+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted trigonal planar geometry to one Na1+ and two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a distorted water-like geometry to one Na1+ and one Sb3+ atom.
- Publication Date:
- Other Number(s):
- mp-29269
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-Na-Sb; NaSbF4; crystal structure
- OSTI Identifier:
- 1203643
- DOI:
- https://doi.org/10.17188/1203643
Citation Formats
Materials Data on NaSbF4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1203643.
Materials Data on NaSbF4 by Materials Project. United States. doi:https://doi.org/10.17188/1203643
2020.
"Materials Data on NaSbF4 by Materials Project". United States. doi:https://doi.org/10.17188/1203643. https://www.osti.gov/servlets/purl/1203643. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1203643,
title = {Materials Data on NaSbF4 by Materials Project},
abstractNote = {NaSbF4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Na1+ is bonded to six F1- atoms to form distorted corner-sharing NaF6 octahedra. The corner-sharing octahedra tilt angles range from 52–64°. There are a spread of Na–F bond distances ranging from 2.30–2.49 Å. Sb3+ is bonded in a 5-coordinate geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 2.00–2.53 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted trigonal planar geometry to two equivalent Na1+ and one Sb3+ atom. In the second F1- site, F1- is bonded in a trigonal planar geometry to two equivalent Na1+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted trigonal planar geometry to one Na1+ and two equivalent Sb3+ atoms. In the fourth F1- site, F1- is bonded in a distorted water-like geometry to one Na1+ and one Sb3+ atom.},
doi = {10.17188/1203643},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}