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Title: Materials Data on Pd(PbCl3)2 by Materials Project

Abstract

Pd(PbCl3)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Pd2+ is bonded in a distorted square co-planar geometry to four Cl1- atoms. There are two shorter (2.33 Å) and two longer (2.34 Å) Pd–Cl bond lengths. Pb2+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of Pb–Cl bond distances ranging from 2.86–3.54 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted trigonal planar geometry to three equivalent Pb2+ atoms. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Pd2+ and three equivalent Pb2+ atoms. In the third Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pd2+ and two equivalent Pb2+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-28982
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Pd(PbCl3)2; Cl-Pb-Pd
OSTI Identifier:
1203037
DOI:
https://doi.org/10.17188/1203037

Citation Formats

The Materials Project. Materials Data on Pd(PbCl3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1203037.
The Materials Project. Materials Data on Pd(PbCl3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1203037
The Materials Project. 2020. "Materials Data on Pd(PbCl3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1203037. https://www.osti.gov/servlets/purl/1203037. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1203037,
title = {Materials Data on Pd(PbCl3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Pd(PbCl3)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Pd2+ is bonded in a distorted square co-planar geometry to four Cl1- atoms. There are two shorter (2.33 Å) and two longer (2.34 Å) Pd–Cl bond lengths. Pb2+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of Pb–Cl bond distances ranging from 2.86–3.54 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted trigonal planar geometry to three equivalent Pb2+ atoms. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Pd2+ and three equivalent Pb2+ atoms. In the third Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pd2+ and two equivalent Pb2+ atoms.},
doi = {10.17188/1203037},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}