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Title: Materials Data on SnF2 by Materials Project

Abstract

SnF2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded to five F1- atoms to form distorted corner-sharing SnF5 square pyramids. There are a spread of Sn–F bond distances ranging from 2.10–2.52 Å. In the second Sn2+ site, Sn2+ is bonded in a 4-coordinate geometry to four F1- atoms. There are a spread of Sn–F bond distances ranging from 2.13–2.67 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two Sn2+ atoms. In the second F1- site, F1- is bonded in a 3-coordinate geometry to three Sn2+ atoms. In the third F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Sn2+ atoms. In the fourth F1- site, F1- is bonded in a linear geometry to two Sn2+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-2843
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SnF2; F-Sn
OSTI Identifier:
1202541
DOI:
https://doi.org/10.17188/1202541

Citation Formats

The Materials Project. Materials Data on SnF2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1202541.
The Materials Project. Materials Data on SnF2 by Materials Project. United States. doi:https://doi.org/10.17188/1202541
The Materials Project. 2020. "Materials Data on SnF2 by Materials Project". United States. doi:https://doi.org/10.17188/1202541. https://www.osti.gov/servlets/purl/1202541. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1202541,
title = {Materials Data on SnF2 by Materials Project},
author = {The Materials Project},
abstractNote = {SnF2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded to five F1- atoms to form distorted corner-sharing SnF5 square pyramids. There are a spread of Sn–F bond distances ranging from 2.10–2.52 Å. In the second Sn2+ site, Sn2+ is bonded in a 4-coordinate geometry to four F1- atoms. There are a spread of Sn–F bond distances ranging from 2.13–2.67 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two Sn2+ atoms. In the second F1- site, F1- is bonded in a 3-coordinate geometry to three Sn2+ atoms. In the third F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Sn2+ atoms. In the fourth F1- site, F1- is bonded in a linear geometry to two Sn2+ atoms.},
doi = {10.17188/1202541},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}