U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sn2P3O10 by Materials Project
Abstract
Sn2P3O10 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Sn+2.50+ is bonded to five O2- atoms to form SnO5 square pyramids that share corners with five PO4 tetrahedra and an edgeedge with one SnO5 square pyramid. There are a spread of Sn–O bond distances ranging from 2.13–2.53 Å. There are three inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent SnO5 square pyramids and corners with two PO4 tetrahedra. There is two shorter (1.51 Å) and two longer (1.59 Å) P–O bond length. In the second P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with four equivalent SnO5 square pyramids and a cornercorner with one PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.52–1.62 Å. In the third P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with four equivalent SnO5 square pyramids and a cornercorner with one PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.53–1.62 Å. There are seven inequivalent O2- sites. In the first O2-more »
- Authors:
- Publication Date:
- Other Number(s):
- mp-26944
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sn2P3O10; O-P-Sn
- OSTI Identifier:
- 1201264
- DOI:
- https://doi.org/10.17188/1201264
Citation Formats
The Materials Project. Materials Data on Sn2P3O10 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1201264.
The Materials Project. Materials Data on Sn2P3O10 by Materials Project. United States. doi:https://doi.org/10.17188/1201264
The Materials Project. 2020.
"Materials Data on Sn2P3O10 by Materials Project". United States. doi:https://doi.org/10.17188/1201264. https://www.osti.gov/servlets/purl/1201264. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1201264,
title = {Materials Data on Sn2P3O10 by Materials Project},
author = {The Materials Project},
abstractNote = {Sn2P3O10 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Sn+2.50+ is bonded to five O2- atoms to form SnO5 square pyramids that share corners with five PO4 tetrahedra and an edgeedge with one SnO5 square pyramid. There are a spread of Sn–O bond distances ranging from 2.13–2.53 Å. There are three inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent SnO5 square pyramids and corners with two PO4 tetrahedra. There is two shorter (1.51 Å) and two longer (1.59 Å) P–O bond length. In the second P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with four equivalent SnO5 square pyramids and a cornercorner with one PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.52–1.62 Å. In the third P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with four equivalent SnO5 square pyramids and a cornercorner with one PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.53–1.62 Å. There are seven inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn+2.50+ and one P5+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Sn+2.50+ and one P5+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn+2.50+ and one P5+ atom. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Sn+2.50+ and one P5+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn+2.50+ and one P5+ atom. In the sixth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the seventh O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms.},
doi = {10.17188/1201264},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}