U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Ce7O12 by Materials Project
Abstract
Ce7O12 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Ce+3.43+ sites. In the first Ce+3.43+ site, Ce+3.43+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Ce–O bond distances ranging from 2.30–2.63 Å. In the second Ce+3.43+ site, Ce+3.43+ is bonded in a distorted octahedral geometry to six equivalent O2- atoms. All Ce–O bond lengths are 2.30 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Ce+3.43+ atoms to form a mixture of corner and edge-sharing OCe4 tetrahedra. In the second O2- site, O2- is bonded to four Ce+3.43+ atoms to form a mixture of distorted corner and edge-sharing OCe4 tetrahedra.
- Publication Date:
- Other Number(s):
- mp-2629
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ce-O; Ce7O12; crystal structure
- OSTI Identifier:
- 1201145
- DOI:
- https://doi.org/10.17188/1201145
Citation Formats
Materials Data on Ce7O12 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1201145.
Materials Data on Ce7O12 by Materials Project. United States. doi:https://doi.org/10.17188/1201145
2020.
"Materials Data on Ce7O12 by Materials Project". United States. doi:https://doi.org/10.17188/1201145. https://www.osti.gov/servlets/purl/1201145. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1201145,
title = {Materials Data on Ce7O12 by Materials Project},
abstractNote = {Ce7O12 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Ce+3.43+ sites. In the first Ce+3.43+ site, Ce+3.43+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Ce–O bond distances ranging from 2.30–2.63 Å. In the second Ce+3.43+ site, Ce+3.43+ is bonded in a distorted octahedral geometry to six equivalent O2- atoms. All Ce–O bond lengths are 2.30 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Ce+3.43+ atoms to form a mixture of corner and edge-sharing OCe4 tetrahedra. In the second O2- site, O2- is bonded to four Ce+3.43+ atoms to form a mixture of distorted corner and edge-sharing OCe4 tetrahedra.},
doi = {10.17188/1201145},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}