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Title: Materials Data on CdCoH18N6Cl5 by Materials Project

Abstract

Co(NH3)6CdCl5 is Halite, Rock Salt structured and crystallizes in the cubic Fd-3c space group. The structure is zero-dimensional and consists of thirty-two azane;cobalt molecules and thirty-two CdCl5 clusters. In each CdCl5 cluster, Cd2+ is bonded in a trigonal bipyramidal geometry to five Cl1- atoms. There are two shorter (2.54 Å) and three longer (2.65 Å) Cd–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Cd2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Cd2+ atom.

Authors:
Publication Date:
Other Number(s):
mp-24430
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CdCoH18N6Cl5; Cd-Cl-Co-H-N
OSTI Identifier:
1200094
DOI:
https://doi.org/10.17188/1200094

Citation Formats

The Materials Project. Materials Data on CdCoH18N6Cl5 by Materials Project. United States: N. p., 2014. Web. doi:10.17188/1200094.
The Materials Project. Materials Data on CdCoH18N6Cl5 by Materials Project. United States. doi:https://doi.org/10.17188/1200094
The Materials Project. 2014. "Materials Data on CdCoH18N6Cl5 by Materials Project". United States. doi:https://doi.org/10.17188/1200094. https://www.osti.gov/servlets/purl/1200094. Pub date:Wed Feb 19 00:00:00 EST 2014
@article{osti_1200094,
title = {Materials Data on CdCoH18N6Cl5 by Materials Project},
author = {The Materials Project},
abstractNote = {Co(NH3)6CdCl5 is Halite, Rock Salt structured and crystallizes in the cubic Fd-3c space group. The structure is zero-dimensional and consists of thirty-two azane;cobalt molecules and thirty-two CdCl5 clusters. In each CdCl5 cluster, Cd2+ is bonded in a trigonal bipyramidal geometry to five Cl1- atoms. There are two shorter (2.54 Å) and three longer (2.65 Å) Cd–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Cd2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Cd2+ atom.},
doi = {10.17188/1200094},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {2}
}