Materials Data on Sb4Cl2O5 by Materials Project
Abstract
Sb4O5Cl2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Sb4O5Cl2 sheet oriented in the (1, 0, 0) direction. there are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 3-coordinate geometry to three O2- and one Cl1- atom. There are a spread of Sb–O bond distances ranging from 2.00–2.10 Å. The Sb–Cl bond length is 2.91 Å. In the second Sb3+ site, Sb3+ is bonded in a 4-coordinate geometry to four O2- and one Cl1- atom. There are a spread of Sb–O bond distances ranging from 1.94–2.48 Å. The Sb–Cl bond length is 3.16 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three Sb3+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the third O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. Cl1- is bonded in a 2-coordinate geometry to two Sb3+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-23419
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sb4Cl2O5; Cl-O-Sb
- OSTI Identifier:
- 1199499
- DOI:
- https://doi.org/10.17188/1199499
Citation Formats
The Materials Project. Materials Data on Sb4Cl2O5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1199499.
The Materials Project. Materials Data on Sb4Cl2O5 by Materials Project. United States. doi:https://doi.org/10.17188/1199499
The Materials Project. 2020.
"Materials Data on Sb4Cl2O5 by Materials Project". United States. doi:https://doi.org/10.17188/1199499. https://www.osti.gov/servlets/purl/1199499. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1199499,
title = {Materials Data on Sb4Cl2O5 by Materials Project},
author = {The Materials Project},
abstractNote = {Sb4O5Cl2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Sb4O5Cl2 sheet oriented in the (1, 0, 0) direction. there are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 3-coordinate geometry to three O2- and one Cl1- atom. There are a spread of Sb–O bond distances ranging from 2.00–2.10 Å. The Sb–Cl bond length is 2.91 Å. In the second Sb3+ site, Sb3+ is bonded in a 4-coordinate geometry to four O2- and one Cl1- atom. There are a spread of Sb–O bond distances ranging from 1.94–2.48 Å. The Sb–Cl bond length is 3.16 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three Sb3+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the third O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. Cl1- is bonded in a 2-coordinate geometry to two Sb3+ atoms.},
doi = {10.17188/1199499},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}