U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Pb3O4 by Materials Project
Abstract
Pb3O4 crystallizes in the tetragonal P4_2/mbc space group. The structure is three-dimensional. there are two inequivalent Pb+2.67+ sites. In the first Pb+2.67+ site, Pb+2.67+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are two shorter (2.18 Å) and four longer (2.25 Å) Pb–O bond lengths. In the second Pb+2.67+ site, Pb+2.67+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.25–2.82 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to four Pb+2.67+ atoms. In the second O2- site, O2- is bonded in a trigonal planar geometry to three Pb+2.67+ atoms.
- Publication Date:
- Other Number(s):
- mp-22633
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; O-Pb; Pb3O4; crystal structure
- OSTI Identifier:
- 1198840
- DOI:
- https://doi.org/10.17188/1198840
Citation Formats
Materials Data on Pb3O4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1198840.
Materials Data on Pb3O4 by Materials Project. United States. doi:https://doi.org/10.17188/1198840
2020.
"Materials Data on Pb3O4 by Materials Project". United States. doi:https://doi.org/10.17188/1198840. https://www.osti.gov/servlets/purl/1198840. Pub date:Fri Jul 17 04:00:00 UTC 2020
@article{osti_1198840,
title = {Materials Data on Pb3O4 by Materials Project},
abstractNote = {Pb3O4 crystallizes in the tetragonal P4_2/mbc space group. The structure is three-dimensional. there are two inequivalent Pb+2.67+ sites. In the first Pb+2.67+ site, Pb+2.67+ is bonded to six O2- atoms to form edge-sharing PbO6 octahedra. There are two shorter (2.18 Å) and four longer (2.25 Å) Pb–O bond lengths. In the second Pb+2.67+ site, Pb+2.67+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.25–2.82 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to four Pb+2.67+ atoms. In the second O2- site, O2- is bonded in a trigonal planar geometry to three Pb+2.67+ atoms.},
doi = {10.17188/1198840},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}
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