U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Eu2SiS4 by Materials Project
Abstract
Eu2SiS4 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. there are two inequivalent Eu2+ sites. In the first Eu2+ site, Eu2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Eu–S bond distances ranging from 2.92–3.48 Å. In the second Eu2+ site, Eu2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Eu–S bond distances ranging from 2.97–3.44 Å. Si4+ is bonded in a tetrahedral geometry to four S2- atoms. All Si–S bond lengths are 2.13 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded to four Eu2+ and one Si4+ atom to form a mixture of distorted face, edge, and corner-sharing SEu4Si square pyramids. In the second S2- site, S2- is bonded in a 5-coordinate geometry to four Eu2+ and one Si4+ atom. In the third S2- site, S2- is bonded in a 1-coordinate geometry to four Eu2+ and one Si4+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-22504
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Eu2SiS4; Eu-S-Si
- OSTI Identifier:
- 1198747
- DOI:
- https://doi.org/10.17188/1198747
Citation Formats
The Materials Project. Materials Data on Eu2SiS4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1198747.
The Materials Project. Materials Data on Eu2SiS4 by Materials Project. United States. doi:https://doi.org/10.17188/1198747
The Materials Project. 2020.
"Materials Data on Eu2SiS4 by Materials Project". United States. doi:https://doi.org/10.17188/1198747. https://www.osti.gov/servlets/purl/1198747. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1198747,
title = {Materials Data on Eu2SiS4 by Materials Project},
author = {The Materials Project},
abstractNote = {Eu2SiS4 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. there are two inequivalent Eu2+ sites. In the first Eu2+ site, Eu2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Eu–S bond distances ranging from 2.92–3.48 Å. In the second Eu2+ site, Eu2+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Eu–S bond distances ranging from 2.97–3.44 Å. Si4+ is bonded in a tetrahedral geometry to four S2- atoms. All Si–S bond lengths are 2.13 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded to four Eu2+ and one Si4+ atom to form a mixture of distorted face, edge, and corner-sharing SEu4Si square pyramids. In the second S2- site, S2- is bonded in a 5-coordinate geometry to four Eu2+ and one Si4+ atom. In the third S2- site, S2- is bonded in a 1-coordinate geometry to four Eu2+ and one Si4+ atom.},
doi = {10.17188/1198747},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}