DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Sn(PbO2)2 by Materials Project

Abstract

Pb2SnO4 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent Pb2+ sites. In the first Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.86 Å. In the second Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.84 Å. Sn4+ is bonded to six O2- atoms to form edge-sharing SnO6 octahedra. There are two shorter (2.08 Å) and four longer (2.14 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two Pb2+ and one Sn4+ atom.

Authors:
Publication Date:
Other Number(s):
mp-22467
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sn(PbO2)2; O-Pb-Sn
OSTI Identifier:
1198329
DOI:
https://doi.org/10.17188/1198329

Citation Formats

The Materials Project. Materials Data on Sn(PbO2)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1198329.
The Materials Project. Materials Data on Sn(PbO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1198329
The Materials Project. 2020. "Materials Data on Sn(PbO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1198329. https://www.osti.gov/servlets/purl/1198329. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1198329,
title = {Materials Data on Sn(PbO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Pb2SnO4 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent Pb2+ sites. In the first Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.86 Å. In the second Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.84 Å. Sn4+ is bonded to six O2- atoms to form edge-sharing SnO6 octahedra. There are two shorter (2.08 Å) and four longer (2.14 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two Pb2+ and one Sn4+ atom.},
doi = {10.17188/1198329},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}