U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sn(PbO2)2 by Materials Project
Abstract
Pb2SnO4 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent Pb2+ sites. In the first Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.86 Å. In the second Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.84 Å. Sn4+ is bonded to six O2- atoms to form edge-sharing SnO6 octahedra. There are two shorter (2.08 Å) and four longer (2.14 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two Pb2+ and one Sn4+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-22467
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sn(PbO2)2; O-Pb-Sn
- OSTI Identifier:
- 1198329
- DOI:
- https://doi.org/10.17188/1198329
Citation Formats
The Materials Project. Materials Data on Sn(PbO2)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1198329.
The Materials Project. Materials Data on Sn(PbO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1198329
The Materials Project. 2020.
"Materials Data on Sn(PbO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1198329. https://www.osti.gov/servlets/purl/1198329. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1198329,
title = {Materials Data on Sn(PbO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Pb2SnO4 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent Pb2+ sites. In the first Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.86 Å. In the second Pb2+ site, Pb2+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Pb–O bond distances ranging from 2.24–2.84 Å. Sn4+ is bonded to six O2- atoms to form edge-sharing SnO6 octahedra. There are two shorter (2.08 Å) and four longer (2.14 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Pb2+ and two equivalent Sn4+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to two Pb2+ and one Sn4+ atom.},
doi = {10.17188/1198329},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}