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Title: Materials Data on Rh17S15 by Materials Project

Abstract

Rh17S15 crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. there are four inequivalent Rh sites. In the first Rh site, Rh is bonded in a rectangular see-saw-like geometry to four S atoms. There are a spread of Rh–S bond distances ranging from 2.31–2.38 Å. In the second Rh site, Rh is bonded in an octahedral geometry to six equivalent S atoms. All Rh–S bond lengths are 2.38 Å. In the third Rh site, Rh is bonded in a distorted rectangular see-saw-like geometry to one Rh and four equivalent S atoms. The Rh–Rh bond length is 2.62 Å. All Rh–S bond lengths are 2.30 Å. In the fourth Rh site, Rh is bonded in a distorted octahedral geometry to two equivalent Rh and four equivalent S atoms. All Rh–S bond lengths are 2.40 Å. There are three inequivalent S sites. In the first S site, S is bonded in a 5-coordinate geometry to five Rh atoms. In the second S site, S is bonded in a 4-coordinate geometry to four Rh atoms. In the third S site, S is bonded in a 5-coordinate geometry to five Rh atoms.

Authors:
Publication Date:
Other Number(s):
mp-21991
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rh17S15; Rh-S
OSTI Identifier:
1197277
DOI:
https://doi.org/10.17188/1197277

Citation Formats

The Materials Project. Materials Data on Rh17S15 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1197277.
The Materials Project. Materials Data on Rh17S15 by Materials Project. United States. doi:https://doi.org/10.17188/1197277
The Materials Project. 2020. "Materials Data on Rh17S15 by Materials Project". United States. doi:https://doi.org/10.17188/1197277. https://www.osti.gov/servlets/purl/1197277. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1197277,
title = {Materials Data on Rh17S15 by Materials Project},
author = {The Materials Project},
abstractNote = {Rh17S15 crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. there are four inequivalent Rh sites. In the first Rh site, Rh is bonded in a rectangular see-saw-like geometry to four S atoms. There are a spread of Rh–S bond distances ranging from 2.31–2.38 Å. In the second Rh site, Rh is bonded in an octahedral geometry to six equivalent S atoms. All Rh–S bond lengths are 2.38 Å. In the third Rh site, Rh is bonded in a distorted rectangular see-saw-like geometry to one Rh and four equivalent S atoms. The Rh–Rh bond length is 2.62 Å. All Rh–S bond lengths are 2.30 Å. In the fourth Rh site, Rh is bonded in a distorted octahedral geometry to two equivalent Rh and four equivalent S atoms. All Rh–S bond lengths are 2.40 Å. There are three inequivalent S sites. In the first S site, S is bonded in a 5-coordinate geometry to five Rh atoms. In the second S site, S is bonded in a 4-coordinate geometry to four Rh atoms. In the third S site, S is bonded in a 5-coordinate geometry to five Rh atoms.},
doi = {10.17188/1197277},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}