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Title: Materials Data on PbS2O3 by Materials Project

Abstract

PbS2O3 crystallizes in the orthorhombic Pbca space group. The structure is two-dimensional and consists of eight hydrogen sulfide molecules and two PbSO3 sheets oriented in the (0, 0, 1) direction. In each PbSO3 sheet, Pb2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.66–3.25 Å. S2+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There is one shorter (1.47 Å) and two longer (1.49 Å) S–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one S2+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one S2+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one S2+ atom.

Publication Date:
Other Number(s):
mp-21904
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; PbS2O3; O-Pb-S
OSTI Identifier:
1197243
DOI:
10.17188/1197243

Citation Formats

The Materials Project. Materials Data on PbS2O3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1197243.
The Materials Project. Materials Data on PbS2O3 by Materials Project. United States. doi:10.17188/1197243.
The Materials Project. 2020. "Materials Data on PbS2O3 by Materials Project". United States. doi:10.17188/1197243. https://www.osti.gov/servlets/purl/1197243. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1197243,
title = {Materials Data on PbS2O3 by Materials Project},
author = {The Materials Project},
abstractNote = {PbS2O3 crystallizes in the orthorhombic Pbca space group. The structure is two-dimensional and consists of eight hydrogen sulfide molecules and two PbSO3 sheets oriented in the (0, 0, 1) direction. In each PbSO3 sheet, Pb2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Pb–O bond distances ranging from 2.66–3.25 Å. S2+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There is one shorter (1.47 Å) and two longer (1.49 Å) S–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one S2+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one S2+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one S2+ atom.},
doi = {10.17188/1197243},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}

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