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Title: Materials Data on RhN3 by Materials Project

Abstract

RhN3 is Skutterudite structured and crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent N1- atoms to form RhN6 octahedra that share corners with six equivalent RhN6 octahedra and corners with twelve equivalent NRh2N2 tetrahedra. The corner-sharing octahedral tilt angles are 75°. All Rh–N bond lengths are 2.09 Å. N1- is bonded to two equivalent Rh3+ and two equivalent N1- atoms to form distorted NRh2N2 tetrahedra that share corners with four equivalent RhN6 octahedra, corners with ten equivalent NRh2N2 tetrahedra, and an edgeedge with one NRh2N2 tetrahedra. The corner-sharing octahedra tilt angles range from 64–65°. There is one shorter (1.47 Å) and one longer (1.54 Å) N–N bond length.

Publication Date:
Other Number(s):
mp-2118
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RhN3; N-Rh
OSTI Identifier:
1196458
DOI:
https://doi.org/10.17188/1196458

Citation Formats

The Materials Project. Materials Data on RhN3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1196458.
The Materials Project. Materials Data on RhN3 by Materials Project. United States. doi:https://doi.org/10.17188/1196458
The Materials Project. 2020. "Materials Data on RhN3 by Materials Project". United States. doi:https://doi.org/10.17188/1196458. https://www.osti.gov/servlets/purl/1196458. Pub date:Wed Jul 22 00:00:00 EDT 2020
@article{osti_1196458,
title = {Materials Data on RhN3 by Materials Project},
author = {The Materials Project},
abstractNote = {RhN3 is Skutterudite structured and crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Rh3+ is bonded to six equivalent N1- atoms to form RhN6 octahedra that share corners with six equivalent RhN6 octahedra and corners with twelve equivalent NRh2N2 tetrahedra. The corner-sharing octahedral tilt angles are 75°. All Rh–N bond lengths are 2.09 Å. N1- is bonded to two equivalent Rh3+ and two equivalent N1- atoms to form distorted NRh2N2 tetrahedra that share corners with four equivalent RhN6 octahedra, corners with ten equivalent NRh2N2 tetrahedra, and an edgeedge with one NRh2N2 tetrahedra. The corner-sharing octahedra tilt angles range from 64–65°. There is one shorter (1.47 Å) and one longer (1.54 Å) N–N bond length.},
doi = {10.17188/1196458},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}