Materials Data on K3Rh(NO2)6 by Materials Project

doi:10.17188/1195486

Title: Materials Data on K3Rh(NO2)6 by Materials Project

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Abstract

K(K(NO2)3)2Rh crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four potassium molecules, four rhodium molecules, and one K(NO2)3 framework. In the K(NO2)3 framework, K1+ is bonded in a distorted q4 geometry to twelve equivalent O2- atoms. All K–O bond lengths are 2.68 Å. N3+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All N–O bond lengths are 2.12 Å. O2- is bonded to two equivalent K1+, two equivalent N3+, and one O2- atom to form a mixture of distorted edge and corner-sharing OK2N2O square pyramids. The O–O bond length is 1.34 Å.

Authors:: The Materials Project

Publication Date:: 2020-07-15

Other Number(s):: mp-20364

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; K3Rh(NO2)6; K-N-O-Rh

OSTI Identifier:: 1195486

DOI:: https://doi.org/10.17188/1195486

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                    The Materials Project. Materials Data on K3Rh(NO2)6 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1195486.

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                    The Materials Project. Materials Data on K3Rh(NO2)6 by Materials Project.  United States.  doi:https://doi.org/10.17188/1195486

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                    The Materials Project. 2020.  
"Materials Data on K3Rh(NO2)6 by Materials Project".  United States.  doi:https://doi.org/10.17188/1195486.  https://www.osti.gov/servlets/purl/1195486. Pub date:Wed Jul 15 00:00:00 EDT 2020

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@article{osti_1195486,

  title        = {Materials Data on K3Rh(NO2)6 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {K(K(NO2)3)2Rh crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four potassium molecules, four rhodium molecules, and one K(NO2)3 framework. In the K(NO2)3 framework, K1+ is bonded in a distorted q4 geometry to twelve equivalent O2- atoms. All K–O bond lengths are 2.68 Å. N3+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All N–O bond lengths are 2.12 Å. O2- is bonded to two equivalent K1+, two equivalent N3+, and one O2- atom to form a mixture of distorted edge and corner-sharing OK2N2O square pyramids. The O–O bond length is 1.34 Å.},

  doi          = {10.17188/1195486},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {7}

}

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DOI: https://doi.org/10.17188/1195486

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