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Title: Materials Data on K2CuPb(NO2)6 by Materials Project

Abstract

K2PbCu(NO2)6 crystallizes in the cubic Fm-3 space group. The structure is three-dimensional and consists of four copper molecules and one K2Pb(NO2)6 framework. In the K2Pb(NO2)6 framework, K1+ is bonded to twelve equivalent O2- atoms to form KO12 cuboctahedra that share edges with six equivalent KO12 cuboctahedra and faces with four equivalent PbO12 cuboctahedra. All K–O bond lengths are 3.17 Å. Pb2+ is bonded to twelve equivalent O2- atoms to form PbO12 cuboctahedra that share faces with eight equivalent KO12 cuboctahedra. All Pb–O bond lengths are 2.83 Å. N3+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.26 Å. O2- is bonded in a single-bond geometry to two equivalent K1+, one Pb2+, and one N3+ atom.

Publication Date:
Other Number(s):
mp-19863
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; K2CuPb(NO2)6; Cu-K-N-O-Pb
OSTI Identifier:
1195055
DOI:
https://doi.org/10.17188/1195055

Citation Formats

The Materials Project. Materials Data on K2CuPb(NO2)6 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1195055.
The Materials Project. Materials Data on K2CuPb(NO2)6 by Materials Project. United States. doi:https://doi.org/10.17188/1195055
The Materials Project. 2020. "Materials Data on K2CuPb(NO2)6 by Materials Project". United States. doi:https://doi.org/10.17188/1195055. https://www.osti.gov/servlets/purl/1195055. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1195055,
title = {Materials Data on K2CuPb(NO2)6 by Materials Project},
author = {The Materials Project},
abstractNote = {K2PbCu(NO2)6 crystallizes in the cubic Fm-3 space group. The structure is three-dimensional and consists of four copper molecules and one K2Pb(NO2)6 framework. In the K2Pb(NO2)6 framework, K1+ is bonded to twelve equivalent O2- atoms to form KO12 cuboctahedra that share edges with six equivalent KO12 cuboctahedra and faces with four equivalent PbO12 cuboctahedra. All K–O bond lengths are 3.17 Å. Pb2+ is bonded to twelve equivalent O2- atoms to form PbO12 cuboctahedra that share faces with eight equivalent KO12 cuboctahedra. All Pb–O bond lengths are 2.83 Å. N3+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.26 Å. O2- is bonded in a single-bond geometry to two equivalent K1+, one Pb2+, and one N3+ atom.},
doi = {10.17188/1195055},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}