U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on VAg3O4 by Materials Project
Abstract
Ag3VO4 crystallizes in the tetragonal I-42m space group. The structure is three-dimensional. V5+ is bonded to four equivalent O2- atoms to form VO4 tetrahedra that share corners with twelve AgO4 tetrahedra. All V–O bond lengths are 1.76 Å. There are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded to four equivalent O2- atoms to form AgO4 tetrahedra that share corners with four equivalent VO4 tetrahedra and corners with eight AgO4 tetrahedra. All Ag–O bond lengths are 2.35 Å. In the second Ag1+ site, Ag1+ is bonded to four equivalent O2- atoms to form distorted AgO4 tetrahedra that share corners with four equivalent VO4 tetrahedra and corners with eight equivalent AgO4 tetrahedra. All Ag–O bond lengths are 2.37 Å. O2- is bonded in a 4-coordinate geometry to one V5+ and three Ag1+ atoms.
- Publication Date:
- Other Number(s):
- mp-19412
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ag-O-V; VAg3O4; crystal structure
- OSTI Identifier:
- 1194423
- DOI:
- https://doi.org/10.17188/1194423
Citation Formats
Materials Data on VAg3O4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1194423.
Materials Data on VAg3O4 by Materials Project. United States. doi:https://doi.org/10.17188/1194423
2020.
"Materials Data on VAg3O4 by Materials Project". United States. doi:https://doi.org/10.17188/1194423. https://www.osti.gov/servlets/purl/1194423. Pub date:Thu Jul 16 04:00:00 UTC 2020
@article{osti_1194423,
title = {Materials Data on VAg3O4 by Materials Project},
abstractNote = {Ag3VO4 crystallizes in the tetragonal I-42m space group. The structure is three-dimensional. V5+ is bonded to four equivalent O2- atoms to form VO4 tetrahedra that share corners with twelve AgO4 tetrahedra. All V–O bond lengths are 1.76 Å. There are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded to four equivalent O2- atoms to form AgO4 tetrahedra that share corners with four equivalent VO4 tetrahedra and corners with eight AgO4 tetrahedra. All Ag–O bond lengths are 2.35 Å. In the second Ag1+ site, Ag1+ is bonded to four equivalent O2- atoms to form distorted AgO4 tetrahedra that share corners with four equivalent VO4 tetrahedra and corners with eight equivalent AgO4 tetrahedra. All Ag–O bond lengths are 2.37 Å. O2- is bonded in a 4-coordinate geometry to one V5+ and three Ag1+ atoms.},
doi = {10.17188/1194423},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}