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Title: Materials Data on Mn(AsO3)2 by Materials Project

Abstract

MnAs2O6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31m space group. The structure is three-dimensional. Mn2+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with twelve equivalent AsO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Mn–O bond lengths are 2.25 Å. As5+ is bonded to six equivalent O2- atoms to form AsO6 octahedra that share corners with six equivalent MnO6 octahedra and edges with three equivalent AsO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All As–O bond lengths are 1.87 Å. O2- is bonded in a distorted trigonal planar geometry to one Mn2+ and two equivalent As5+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-19409
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Mn(AsO3)2; As-Mn-O
OSTI Identifier:
1194419
DOI:
https://doi.org/10.17188/1194419

Citation Formats

The Materials Project. Materials Data on Mn(AsO3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1194419.
The Materials Project. Materials Data on Mn(AsO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1194419
The Materials Project. 2020. "Materials Data on Mn(AsO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1194419. https://www.osti.gov/servlets/purl/1194419. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1194419,
title = {Materials Data on Mn(AsO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {MnAs2O6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31m space group. The structure is three-dimensional. Mn2+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with twelve equivalent AsO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Mn–O bond lengths are 2.25 Å. As5+ is bonded to six equivalent O2- atoms to form AsO6 octahedra that share corners with six equivalent MnO6 octahedra and edges with three equivalent AsO6 octahedra. The corner-sharing octahedral tilt angles are 52°. All As–O bond lengths are 1.87 Å. O2- is bonded in a distorted trigonal planar geometry to one Mn2+ and two equivalent As5+ atoms.},
doi = {10.17188/1194419},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}