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Title: Materials Data on Na5NiSO2 by Materials Project

Abstract

Na5NiSO2 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Na1+ sites. In the first Na1+ site, Na1+ is bonded in a 2-coordinate geometry to two equivalent S2- and two equivalent O2- atoms. Both Na–S bond lengths are 3.02 Å. Both Na–O bond lengths are 2.31 Å. In the second Na1+ site, Na1+ is bonded in a linear geometry to four equivalent S2- and two equivalent O2- atoms. All Na–S bond lengths are 3.24 Å. Both Na–O bond lengths are 2.29 Å. Ni1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ni–O bond lengths are 1.80 Å. S2- is bonded to twelve Na1+ atoms to form SNa12 cuboctahedra that share corners with four equivalent SNa12 cuboctahedra, faces with four equivalent SNa12 cuboctahedra, and faces with eight equivalent ONa5Ni octahedra. O2- is bonded to five Na1+ and one Ni1+ atom to form ONa5Ni octahedra that share corners with six equivalent ONa5Ni octahedra and faces with four equivalent SNa12 cuboctahedra. The corner-sharing octahedra tilt angles range from 0–16°.

Publication Date:
Other Number(s):
mp-18912
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Na5NiSO2; Na-Ni-O-S
OSTI Identifier:
1193650
DOI:
https://doi.org/10.17188/1193650

Citation Formats

The Materials Project. Materials Data on Na5NiSO2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1193650.
The Materials Project. Materials Data on Na5NiSO2 by Materials Project. United States. doi:https://doi.org/10.17188/1193650
The Materials Project. 2020. "Materials Data on Na5NiSO2 by Materials Project". United States. doi:https://doi.org/10.17188/1193650. https://www.osti.gov/servlets/purl/1193650. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1193650,
title = {Materials Data on Na5NiSO2 by Materials Project},
author = {The Materials Project},
abstractNote = {Na5NiSO2 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Na1+ sites. In the first Na1+ site, Na1+ is bonded in a 2-coordinate geometry to two equivalent S2- and two equivalent O2- atoms. Both Na–S bond lengths are 3.02 Å. Both Na–O bond lengths are 2.31 Å. In the second Na1+ site, Na1+ is bonded in a linear geometry to four equivalent S2- and two equivalent O2- atoms. All Na–S bond lengths are 3.24 Å. Both Na–O bond lengths are 2.29 Å. Ni1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ni–O bond lengths are 1.80 Å. S2- is bonded to twelve Na1+ atoms to form SNa12 cuboctahedra that share corners with four equivalent SNa12 cuboctahedra, faces with four equivalent SNa12 cuboctahedra, and faces with eight equivalent ONa5Ni octahedra. O2- is bonded to five Na1+ and one Ni1+ atom to form ONa5Ni octahedra that share corners with six equivalent ONa5Ni octahedra and faces with four equivalent SNa12 cuboctahedra. The corner-sharing octahedra tilt angles range from 0–16°.},
doi = {10.17188/1193650},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}