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Title: Materials Data on RbAg2SbS4 by Materials Project

Abstract

RbAg2SbS4 crystallizes in the trigonal P3_221 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Rb–S bond distances ranging from 3.42–3.53 Å. Ag1+ is bonded in a distorted rectangular see-saw-like geometry to four S2- atoms. There are a spread of Ag–S bond distances ranging from 2.54–2.74 Å. Sb5+ is bonded in a tetrahedral geometry to four S2- atoms. All Sb–S bond lengths are 2.39 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to two equivalent Rb1+, two equivalent Ag1+, and one Sb5+ atom to form a mixture of distorted edge and corner-sharing SRb2Ag2Sb trigonal bipyramids. In the second S2- site, S2- is bonded in a 5-coordinate geometry to two equivalent Rb1+, two equivalent Ag1+, and one Sb5+ atom.

Publication Date:
Other Number(s):
mp-17756
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbAg2SbS4; Ag-Rb-S-Sb
OSTI Identifier:
1192674
DOI:
https://doi.org/10.17188/1192674

Citation Formats

The Materials Project. Materials Data on RbAg2SbS4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1192674.
The Materials Project. Materials Data on RbAg2SbS4 by Materials Project. United States. doi:https://doi.org/10.17188/1192674
The Materials Project. 2020. "Materials Data on RbAg2SbS4 by Materials Project". United States. doi:https://doi.org/10.17188/1192674. https://www.osti.gov/servlets/purl/1192674. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1192674,
title = {Materials Data on RbAg2SbS4 by Materials Project},
author = {The Materials Project},
abstractNote = {RbAg2SbS4 crystallizes in the trigonal P3_221 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are a spread of Rb–S bond distances ranging from 3.42–3.53 Å. Ag1+ is bonded in a distorted rectangular see-saw-like geometry to four S2- atoms. There are a spread of Ag–S bond distances ranging from 2.54–2.74 Å. Sb5+ is bonded in a tetrahedral geometry to four S2- atoms. All Sb–S bond lengths are 2.39 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to two equivalent Rb1+, two equivalent Ag1+, and one Sb5+ atom to form a mixture of distorted edge and corner-sharing SRb2Ag2Sb trigonal bipyramids. In the second S2- site, S2- is bonded in a 5-coordinate geometry to two equivalent Rb1+, two equivalent Ag1+, and one Sb5+ atom.},
doi = {10.17188/1192674},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}