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Title: Materials Data on Yb11Sb10 by Materials Project

Abstract

Yb11Sb10 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are four inequivalent Yb+2.73+ sites. In the first Yb+2.73+ site, Yb+2.73+ is bonded in a 7-coordinate geometry to seven Sb3- atoms. There are a spread of Yb–Sb bond distances ranging from 3.19–3.45 Å. In the second Yb+2.73+ site, Yb+2.73+ is bonded to seven Sb3- atoms to form a mixture of distorted edge, face, and corner-sharing YbSb7 pentagonal bipyramids. There are a spread of Yb–Sb bond distances ranging from 3.16–3.55 Å. In the third Yb+2.73+ site, Yb+2.73+ is bonded to seven Sb3- atoms to form a mixture of distorted edge, face, and corner-sharing YbSb7 pentagonal bipyramids. There are a spread of Yb–Sb bond distances ranging from 2.97–3.73 Å. In the fourth Yb+2.73+ site, Yb+2.73+ is bonded in a 9-coordinate geometry to nine Sb3- atoms. There are a spread of Yb–Sb bond distances ranging from 3.51–3.61 Å. There are five inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 10-coordinate geometry to eight Yb+2.73+ and two Sb3- atoms. There are one shorter (2.94 Å) and one longer (3.34 Å) Sb–Sb bond lengths. In the second Sb3- site, Sb3- is bonded in a 8-coordinate geometry tomore » eight Yb+2.73+ atoms. In the third Sb3- site, Sb3- is bonded in a 11-coordinate geometry to seven Yb+2.73+ and four Sb3- atoms. Both Sb–Sb bond lengths are 3.03 Å. In the fourth Sb3- site, Sb3- is bonded in a 9-coordinate geometry to nine Yb+2.73+ atoms. In the fifth Sb3- site, Sb3- is bonded in a 8-coordinate geometry to eight Yb+2.73+ atoms.« less

Authors:
Publication Date:
Other Number(s):
mp-17402
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Yb11Sb10; Sb-Yb
OSTI Identifier:
1192491
DOI:
https://doi.org/10.17188/1192491

Citation Formats

The Materials Project. Materials Data on Yb11Sb10 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1192491.
The Materials Project. Materials Data on Yb11Sb10 by Materials Project. United States. doi:https://doi.org/10.17188/1192491
The Materials Project. 2020. "Materials Data on Yb11Sb10 by Materials Project". United States. doi:https://doi.org/10.17188/1192491. https://www.osti.gov/servlets/purl/1192491. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1192491,
title = {Materials Data on Yb11Sb10 by Materials Project},
author = {The Materials Project},
abstractNote = {Yb11Sb10 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are four inequivalent Yb+2.73+ sites. In the first Yb+2.73+ site, Yb+2.73+ is bonded in a 7-coordinate geometry to seven Sb3- atoms. There are a spread of Yb–Sb bond distances ranging from 3.19–3.45 Å. In the second Yb+2.73+ site, Yb+2.73+ is bonded to seven Sb3- atoms to form a mixture of distorted edge, face, and corner-sharing YbSb7 pentagonal bipyramids. There are a spread of Yb–Sb bond distances ranging from 3.16–3.55 Å. In the third Yb+2.73+ site, Yb+2.73+ is bonded to seven Sb3- atoms to form a mixture of distorted edge, face, and corner-sharing YbSb7 pentagonal bipyramids. There are a spread of Yb–Sb bond distances ranging from 2.97–3.73 Å. In the fourth Yb+2.73+ site, Yb+2.73+ is bonded in a 9-coordinate geometry to nine Sb3- atoms. There are a spread of Yb–Sb bond distances ranging from 3.51–3.61 Å. There are five inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 10-coordinate geometry to eight Yb+2.73+ and two Sb3- atoms. There are one shorter (2.94 Å) and one longer (3.34 Å) Sb–Sb bond lengths. In the second Sb3- site, Sb3- is bonded in a 8-coordinate geometry to eight Yb+2.73+ atoms. In the third Sb3- site, Sb3- is bonded in a 11-coordinate geometry to seven Yb+2.73+ and four Sb3- atoms. Both Sb–Sb bond lengths are 3.03 Å. In the fourth Sb3- site, Sb3- is bonded in a 9-coordinate geometry to nine Yb+2.73+ atoms. In the fifth Sb3- site, Sb3- is bonded in a 8-coordinate geometry to eight Yb+2.73+ atoms.},
doi = {10.17188/1192491},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}