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Title: Materials Data on Rh2O3 by Materials Project

Abstract

Rh2O3 is Corundum-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Rh3+ is bonded to six O2- atoms to form a mixture of face, edge, and corner-sharing RhO6 octahedra. The corner-sharing octahedra tilt angles range from 48–71°. There are a spread of Rh–O bond distances ranging from 2.02–2.14 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing ORh4 trigonal pyramids. In the second O2- site, O2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing ORh4 tetrahedra.

Authors:
Publication Date:
Other Number(s):
mp-1716
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rh2O3; O-Rh
OSTI Identifier:
1192363
DOI:
https://doi.org/10.17188/1192363

Citation Formats

The Materials Project. Materials Data on Rh2O3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1192363.
The Materials Project. Materials Data on Rh2O3 by Materials Project. United States. doi:https://doi.org/10.17188/1192363
The Materials Project. 2020. "Materials Data on Rh2O3 by Materials Project". United States. doi:https://doi.org/10.17188/1192363. https://www.osti.gov/servlets/purl/1192363. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1192363,
title = {Materials Data on Rh2O3 by Materials Project},
author = {The Materials Project},
abstractNote = {Rh2O3 is Corundum-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Rh3+ is bonded to six O2- atoms to form a mixture of face, edge, and corner-sharing RhO6 octahedra. The corner-sharing octahedra tilt angles range from 48–71°. There are a spread of Rh–O bond distances ranging from 2.02–2.14 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing ORh4 trigonal pyramids. In the second O2- site, O2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing ORh4 tetrahedra.},
doi = {10.17188/1192363},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}