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Title: Materials Data on Re2SbO6 by Materials Project

Abstract

SbRe2O6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Re+4.50+ is bonded to six O2- atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedra tilt angles range from 34–43°. There are a spread of Re–O bond distances ranging from 1.94–2.05 Å. Sb3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.05 Å) and two longer (2.21 Å) Sb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to one Re+4.50+ and two equivalent Sb3+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Re+4.50+ atoms. In the third O2- site, O2- is bonded in a 3-coordinate geometry to three equivalent Re+4.50+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-15910
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Re2SbO6; O-Re-Sb
OSTI Identifier:
1191456
DOI:
https://doi.org/10.17188/1191456

Citation Formats

The Materials Project. Materials Data on Re2SbO6 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1191456.
The Materials Project. Materials Data on Re2SbO6 by Materials Project. United States. doi:https://doi.org/10.17188/1191456
The Materials Project. 2020. "Materials Data on Re2SbO6 by Materials Project". United States. doi:https://doi.org/10.17188/1191456. https://www.osti.gov/servlets/purl/1191456. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1191456,
title = {Materials Data on Re2SbO6 by Materials Project},
author = {The Materials Project},
abstractNote = {SbRe2O6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Re+4.50+ is bonded to six O2- atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedra tilt angles range from 34–43°. There are a spread of Re–O bond distances ranging from 1.94–2.05 Å. Sb3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.05 Å) and two longer (2.21 Å) Sb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to one Re+4.50+ and two equivalent Sb3+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Re+4.50+ atoms. In the third O2- site, O2- is bonded in a 3-coordinate geometry to three equivalent Re+4.50+ atoms.},
doi = {10.17188/1191456},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}